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Safety Information

A6756

Sigma-Aldrich

Sodium arsenate dibasic heptahydrate

≥98.0%

Synonym(s):

Disodium hydrogen arsenate heptahydrate, di-Sodium hydrogen arsenate heptahydrate

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About This Item

Linear Formula:
Na2HAsO4 · 7H2O
CAS Number:
10048-95-0
Molecular Weight:
312.01
MDL number:
MFCD00149179
UNSPSC Code:
12352302
PubChem Substance ID:
24891135
NACRES:
NA.21
Assay:
≥98.0%
form:
powder

Quality Level

200

Assay

≥98.0%

form

powder

reaction suitability

reagent type: catalyst
core: arsenic

pH

8.5-9.0 (25 °C, 50 g/L)

SMILES string

O.O.O.O.O.O.O.[Na+].[Na+].O[As]([O-])([O-])=O

InChI

1S/AsH3O4.2Na.7H2O/c2-1(3,4)5;;;;;;;;;/h(H3,2,3,4,5);;;7*1H2/q;2*+1;;;;;;;/p-2

InChI key

KOLXPEJIBITWIQ-UHFFFAOYSA-L

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General description

Sodium arsenate dibasic heptahydrate (As(V)) is an arsenic compound.

Application

Sodium arsenate dibasic heptahydrate may be used as a reference standard for the quantification of arsenic compounds in rice- and seafood-based samples by ion chromatography-inductively coupled plasma/ mass spectrometry. The samples for analysis were prepared by ultrasonic-assisted enzymatic extraction (UAEE).

Signal Word

Danger

Hazard Statements

H301 + H331,H350,H410

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Poisonous substance

PRTR

Specified Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

A6756-100G-PW:
A6756-50G:4548173186979
A6756-100G-LBL:
A6756-100G:4548173186962
A6756-BULK:
A6756-5G:4548173275482
A6756-VAR:
A6756-50G-PW:

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Certificates of Analysis (COA)

Lot/Batch Number
0000403552
0000355306
0000355306
0000343135
0000403552

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Validation of a method for arsenic speciation in food by ion chromatography-inductively coupled plasma/mass spectrometry after ultrasonic-assisted enzymatic extraction.
Dufailly V, et al.
Journal of AOAC (Association of Official Analytical Chemists) International, 94(3), 947-958 (2011)
Shugo Suzuki et al.
Toxicology, 299(2-3), 155-159 (2012-06-06)
Inorganic arsenic is a known human carcinogen, inducing tumors of the skin, urinary bladder and lung. It is metabolized to organic methylated arsenicals. 2,3-Dimercaptopropane-1-sulfonic acid (DMPS), a chelating agent, is capable of reducing pentavalent arsenicals to the trivalent state and
Tatyana S Pinyayev et al.
Chemical research in toxicology, 24(4), 475-477 (2011-03-11)
The conventional scheme for arsenic methylation accounts for methylated oxyarsenical production but not for thioarsenical formation. Here, we report that in vitro anaerobic microbiota of mouse cecum converts arsenate into oxy- and thio- arsenicals. Besides methylarsonic acid (MMA(V)), arsenate was
Takayuki Watanabe et al.
Archives of toxicology, 85(6), 577-588 (2011-05-04)
It has been suggested that arsenic (+3 oxidation state) methyltransferase (AS3MT) plays a critical role in methylation of arsenic, and that arsenic-glutathione conjugate is a substrate for AS3MT-catalyzed methylation of arsenic. However, the mechanism of arsenic methylation in cells is
Martin P Pothier et al.
Frontiers in microbiology, 9, 2310-2310 (2018-10-20)
Despite its high toxicity and widespread occurrence in many parts of the world, arsenic (As) concentrations in decentralized water supplies such as domestic wells remain often unquantified. One limitation to effective monitoring is the high cost and lack of portability
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