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160504

Sigma-Aldrich

9-Fluorenemethanol

99%

Synonym(s):

9-(Hydroxymethyl)fluorene, 9-Fluorenylmethanol

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About This Item

Empirical Formula (Hill Notation):
C14H12O
CAS Number:
24324-17-2
Molecular Weight:
196.24
Beilstein:
2330017
EC Number:
246-167-5
MDL number:
MFCD00001139
UNSPSC Code:
12352100
PubChem Substance ID:
24849874
NACRES:
NA.22

Assay

99%

form

solid

mp

105-107 °C (lit.)

solubility

methanol: soluble 50 mg/mL, clear (very hazy colorless to yellow and Colorless to Green-Yellow)

SMILES string

OCC1c2ccccc2-c3ccccc13

InChI

1S/C14H12O/c15-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14-15H,9H2

InChI key

XXSCONYSQQLHTH-UHFFFAOYSA-N

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General description

Vibrational spectroscopy of jet-cooled 9-fluorenemethanol and its clusters 9-fluorenemethanol-H2O, 9-fluorenemethanol-CH3OH, 9-fluorenemethanol-C2H5OH and 9-fluorenemethanol-C3H7OH has been studied by IR-UV double-resonance method. Electropolymerization of 9-fluorenemethanol in boron trifluoride diethyl etherate leads to low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) (PFMO) film.

Application

9-Fluorenemethanol, N-protecting reagent, was used in the peptide syntheses. 9-Fluorenemethanol was also used in the synthesis of deoxynucleoside 9-fluorenemethyl phosphorodithioates.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis, 119-119 (1990)
2'-Deoxynucleoside Dithiophosphates: Synthesis and Biological Studies1.
Seeberger PH, et al.
Journal of the American Chemical Society, 117(5), 1472-1478 (1995)
Swarna Basu et al.
The Journal of chemical physics, 120(12), 5631-5641 (2004-07-23)
Vibrational spectroscopy of jet-cooled 9-fluorenemethanol and its clusters 9-fluorenemethanol-H2O, 9-fluorenemethanol-CH3OH, 9-fluorenemethanol-C2H5OH, and 9-fluorenemethanol-C3H7OH has been carried out using an IR-UV double-resonance method. The spectrum of the OH stretching vibration, v(OH), has been measured for the 9-fluorenemethanol monomer and for each
The Journal of Organic Chemistry, 57, 6421-6421 (1992)
Low-potential electrosynthesis of novel electroactive poly (9-fluorenemethanol) and its electrochromic and blue-light-emitting properties.
Zhang S, et al.
Electrochimica Acta, 90, 452-460 (2013)
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