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175390

Sigma-Aldrich

Triphenylcarbenium pentachlorostannate

Synonym(s):

Trityl pentachlorostannate

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About This Item

Linear Formula:
(C6H5)3CSnCl5
CAS Number:
15414-98-9
Molecular Weight:
539.30
EC Number:
239-426-9
MDL number:
MFCD00000512
UNSPSC Code:
12352101
PubChem Substance ID:
24850498
NACRES:
NA.22

Quality Level

100

SMILES string

Cl[Sn-](Cl)(Cl)(Cl)Cl.c1ccc(cc1)[C+](c2ccccc2)c3ccccc3

InChI

1S/C19H15.5ClH.Sn/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;;;/h1-15H;5*1H;/q+1;;;;;;+4/p-5

InChI key

LJHTYNWDYRJYIH-UHFFFAOYSA-I

Application

Triphenylcarbenium pentachlorostannate can be used:
  • In the study of cationic polymerization reactions of 3,6-dibromo-9-(2,3-epoxypropyl)carbazole using the microcalorimetric technique.
  • In the synthesis of diarylcyclohexanones, the key intermediates for the preparation of antiprotozoals.
  • As an initiator in the photopolymerization of carbazolyl derived epoxy monomers.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302 + H312 + H332,H314

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Diarylcyclohexanones: synthons for new bicyclic compounds
Ahmad S, et al.
Monatshefte fur Chemie / Chemical Monthly, 143(1), 145-152 (2012)
Cationic ring-opening polymerization of carbazolyl-containing epoxy monomers by triphenyl carbenium salts as thermal-and photolatent initiators
Lazauskaite R, et al.
Monatshefte fur Chemie / Chemical Monthly, 140(5), 565-565 (2009)
Polymerization of 3, 6-dibromo-9-(2, 3-epoxypropyl) carbazole with triphenylcarbenium salts
Gravzulevivcius JV, et al.
European Polymer Journal, 28(5), 539-545 (1992)

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