All Photos(3)
About This Item
Linear Formula:
NH2COOCH3
CAS Number:
Molecular Weight:
75.07
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
98%
form
crystals
bp
176-177 °C (lit.)
mp
56-58 °C (lit.)
solubility
alcohol: freely soluble(lit.)
water: freely soluble(lit.)
functional group
amine
SMILES string
COC(N)=O
InChI
1S/C2H5NO2/c1-5-2(3)4/h1H3,(H2,3,4)
InChI key
GTCAXTIRRLKXRU-UHFFFAOYSA-N
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Application
Methyl carbamate was used in the synthesis of protected aminocyclopropanes.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Shingo Ishikawa et al.
Angewandte Chemie (International ed. in English), 52(38), 10060-10063 (2013-08-06)
Easy as 1,2,3: Reaction of methyl carbamate, triethyl orthoformate, and readily available alkenes provides a highly practical preparation of protected aminocyclopropanes. The reaction proceeds with preferential cis addition to alkenes, and cleavage of the methyl carbamate gives the free aminocyclopropanes
Joshua A Hartsel et al.
Bioorganic & medicinal chemistry letters, 22(14), 4593-4598 (2012-06-29)
To identify potential human-safe insecticides against the malaria mosquito we undertook an investigation of the structure-activity relationship of aryl methylcarbamates inhibitors of acetylcholinesterase (AChE). Compounds bearing a β-branched 2-alkoxy or 2-thioalkyl group were found to possess good selectivity for inhibition
Xiangyun Lin et al.
Journal of separation science, 34(2), 202-209 (2011-01-20)
This paper described a simple, rapid and efficient method for the determination of N-methyl carbamate pesticides in tomato, cucumber, carrot and lettuce samples by dispersive liquid-liquid microextraction coupled with HPLC-diode array detection. Some experimental parameters that influenced the extraction efficiency
D F K Rawn et al.
Food additives and contaminants, 21(6), 555-563 (2004-06-19)
Infants and young children consume fruit juices and drinks at rates exceeding those of older children and adults. Carbamate pesticides are known to be used on a broad spectrum of crops, including orchard and vine crops such as apples and
Methyl carbamate: negative results in mouse bone-marrow micronucleus test.
M D Shelby et al.
Mutation research, 260(4), 311-311 (1991-08-01)
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