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372331

Sigma-Aldrich

Ammonium acetate

99.999% trace metals basis

Synonym(s):

Ammonium ethanoate

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About This Item

Linear Formula:
CH3CO2NH4
CAS Number:
Molecular Weight:
77.08
Beilstein:
4186741
EC Number:
MDL number:
UNSPSC Code:
12352302
eCl@ss:
39021908
PubChem Substance ID:
NACRES:
NA.23

Assay

99.999% trace metals basis

form

crystalline
solid

technique(s)

HPLC: suitable

impurities

≤20.0 ppm Trace Metal Analysis

mp

110-112 °C (dec.) (lit.)

SMILES string

N.CC(O)=O

InChI

1S/C2H4O2.H3N/c1-2(3)4;/h1H3,(H,3,4);1H3

InChI key

USFZMSVCRYTOJT-UHFFFAOYSA-N

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General description

Ammonium acetate is a white crystalline water-soluble ammonium salt with unique properties that make it suitable for use in solar cells, batteries, and fuel cell catalysts.

Application

Ammonium acetate can be used:
  • To passivate CsPbI3 perovskite nanocrystals for red LEDs. Ammonium acetate effectively eliminate undesired surface metallic lead cations and dangling bonds to enhance the stability and photoluminescence quantum yield (PLQY).
  • As an additive to fabricate high quality perovskite solar cell with enhanced power conversion efficiency (PCE) of 13.9%. It promotes crystallization and improve performance without changing the perovskite composition.
  • As a cost effective and green electrolyte for all-organic battery-supercapacitor hybrid device with maximum energy density.
  • As an electrolyte additive for aqueous zinc batteries. It helps to improve cycling stability and capacity retention.

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Reactions of phenanthraquinone and retenequinone with aldehydes and ammonium acetate in acetic acid solution1.
Steck EA and Day AR.
Journal of the American Chemical Society, 65(3), 452-456 (1943)
Selective inhibition of benzyl ether hydrogenolysis with Pd/C due to the presence of ammonia, pyridine or ammonium acetate.
Sajiki H.
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