482285
Rhodium(II) acetate dimer
99.9% trace metals basis
Synonym(s):
Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)
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All Photos(3)
About This Item
Linear Formula:
Rh2(OOCCH3)4
CAS Number:
Molecular Weight:
441.99
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
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Quality Level
Assay
99.9% trace metals basis
form
powder
reaction suitability
reaction type: C-H Activation
reagent type: catalyst
SMILES string
CC(=O)O[Rh]OC(C)=O.CC(=O)O[Rh]OC(C)=O
InChI
1S/4C2H4O2.2Rh/c4*1-2(3)4;;/h4*1H3,(H,3,4);;/q;;;;2*+2/p-4
InChI key
SYBXSZMNKDOUCA-UHFFFAOYSA-J
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Related Categories
Application
Catalyst for Rh-mediated C-H activation
Effective catalyst for ylide formation.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Rhodium carbenoid mediated C-H activation of a tertiary methyl group: an enantiospecific approach to the angular triquinanes norsilphiperfolane and norcameroonanes
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Synlett, 16, 2343-2346 (2011)
Dirk V Deubel
Journal of the American Chemical Society, 130(2), 665-675 (2007-12-19)
The cause of mutations in the genome by the occurrence of nuclebases in their rare tautomeric forms was first proposed by Watson and Crick in 1953. Since this pioneering proposal, tremendous experimental and theoretical research efforts have aimed to elucidate
J R Rubin et al.
Journal of biomolecular structure & dynamics, 2(3), 525-530 (1984-12-01)
A crystalline complex of yeast tRNA(phe) and dirhodium tetraacetate (DRTA) was prepared and its X-ray structure determined. The bifunctional DRTA forms an intermolecular cross-link between the N(1) position of adenine A36 in the anticodon triplet and possibly a ribose hydroxyl
Jin Wang et al.
Organic letters, 13(4), 700-702 (2011-01-18)
Vinyl diazophosphonates can be stereoselectively synthesized and, depending upon their substitution pattern, undergo intramolecular C-H insertion reactions or sulfonium ylide rearrangements when exposed to Rh(2)(OAc)(4).
L Trynda et al.
Journal of inorganic biochemistry, 58(1), 69-77 (1995-04-01)
The interaction of Rh2(OAc)4 with human serum albumin (HSA) has been studied by absorption difference spectroscopy, CD spectroscopy, and quantitative precipitating HSA-antibody test. Our results demonstrate that this rhodium complex reacts easily with HSA at several ratios of reagents. The
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