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Key Documents

751138

Sigma-Aldrich

1-(Methoxycarbonyl)ethyl benzodithioate

≥97%

Synonym(s):

2-[(Phenylthioxomethyl)thio]propanoic acid methyl ester

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About This Item

Empirical Formula (Hill Notation):
C11H12O2S2
CAS Number:
Molecular Weight:
240.34
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

≥97%

form

liquid

refractive index

n20/D 1.6288

bp

275.2-284.4 °C

density

1.1777 g/mL at 25 °C

storage temp.

2-8°C

InChI

1S/C11H12O2S2/c1-8(10(12)13-2)15-11(14)9-6-4-3-5-7-9/h3-8H,1-2H3

InChI key

WPFPXUQEUXJYHU-UHFFFAOYSA-N

Application

RAFT agent for controlled radical polymerization; well-suited for polymerization of methacrylates, methacrylamides, and to a lesser extent styrenes, acrylates, and acrylamides. Chain Transfer Agent (CTA)

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Articles

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Protocols

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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