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07672

Sigma-Aldrich

N,N-Diethyl-p-phenylenediamine sulfate salt

≥98.0% (T)

Synonym(s):

4-Amino-N,N-diethylaniline sulfate salt

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About This Item

Linear Formula:
(C2H5)2NC6H4NH2 · H2SO4
CAS Number:
Molecular Weight:
262.33
Beilstein:
4219768
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

≥98.0% (T)

form

solid

mp

184-186 °C (lit.)
184-187 °C

functional group

amine

SMILES string

OS(O)(=O)=O.CCN(CC)c1ccc(N)cc1

InChI

1S/C10H16N2.H2O4S/c1-3-12(4-2)10-7-5-9(11)6-8-10;1-5(2,3)4/h5-8H,3-4,11H2,1-2H3;(H2,1,2,3,4)

InChI key

AYLDJQABCMPYEN-UHFFFAOYSA-N

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Application

N,N-Diethyl-p-phenylenediamine sulfate salt has been used to prepare N,N-diethyl-p-phenylenediamine (DPD) solution, which is commonly used as a chromogenic indicator for the determination of free and total chlorine by titrimetric, colorimetric and spectroscopic methods.{50

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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An improved N, N?-diethyl-p-phenylenediamine (DPD) method for the determination of free chlorine based on multiple wavelength detection.
Moberg L & Karlberg B
Analytica Chimica Acta, 407(1-2), 127-133 (2000)
Improvements in the N, N-diethyl-p-phenylenediamine method for the determination of free and combined residual chlorine through the use of FIA.
Gordon G, et al.
Talanta, 38(2), 145-149 (1991)
Joanne Paquin et al.
Arzneimittel-Forschung, 55(7), 359-369 (2005-08-06)
Oxidative stress may involve overproduction of hydrogen peroxide which can generate highly cytotoxic hydroxyl radicals in the presence of ferrous ions. This work demonstrates that TCAT (Tricomponent Antioxidant Therapy), an association of pyruvate, vitamin E and fatty acids, provides neuronal
Masoumeh Hasani et al.
Journal of hazardous materials, 157(1), 161-169 (2008-02-15)
A multicomponent analysis method based on principal component analysis-artificial neural network models (PC-ANN) is proposed for the determination of phenolic compounds. The method relies on the oxidative coupling of phenols (phenol, 2 chlorophenol, 3-chlorophenol and 4-chlorophenol) to N,N-diethyl-p-phenylenediamine in the
Allergic contact dermatitis in a photographer.
A Aguirre et al.
Contact dermatitis, 27(5), 340-341 (1992-11-01)

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