107840

2,2,2-Trifluoroacetophenone

99%

• 동의어(들): α,α,α-Trifluoroacetophenone, Phenyl trifluoromethyl ketone
• Linear Formula: CF₃COC₆H₅
• CAS Number: 434-45-7
• Molecular Weight: 174.12
• Beilstein: 1866286
• EC Number: 207-103-1
• MDL number: MFCD00000420
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24846784
• NACRES: NA.22

속성

• Quality Level: 200
• 분석: 99%
• refractive index: n20/D 1.458 (lit.)
• bp: 165-166 °C (lit.); 46-48 °C/14 mmHg (lit.)
• density: 1.24 g/mL at 25 °C (lit.)
• SMILES string: FC(F)(F)C(=O)c1ccccc1
• InChI: 1S/C8H5F3O/c9-8(10,11)7(12)6-4-2-1-3-5-6/h1-5H
• InChI key: KZJRKRQSDZGHEC-UHFFFAOYSA-N

설명

일반 설명

2,2,2-Trifluoroacetophenone is the starting material for the synthesis of f 3-trifluoromethyl-3-phenyldiazirine. It undergoes asymmetric reduction with optically active Grignard reagent to form 2,2,2-trifluoro-1-phenylethanol. It undergoes condensation with biphenyl, terphenyl, a mixture of biphenyl with terphenyl, phenyl ether and diphenoxybenzophenone to form new aromatic 3F polymers.

2,2,2-trifluoroacetophenone is used as an organocatalyst for the oxidation of tertiary amines and azines to N-oxidesalkenes.

애플리케이션

2,2,2-Trifluoroacetophenone was used in the synthesis of new fluorinated polymers, having high average molecular weight, high thermal stability and good film-forming properties.

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H226,H315,H319,H335
• 예방조치 성명서: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): 105.8 °F - closed cup
• Flash Point (°C): 41 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter