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Merck
모든 사진(3)

문서

132004

Sigma-Aldrich

p-Toluenesulfonyl hydrazide

97%

동의어(들):

p-Toluenesulfonhydrazide, p-Toluenesulfonic acid hydrazide, p-Toluenesulfonyl hydrazide, Tosylhydrazide

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About This Item

Linear Formula:
CH3C6H4SO2NHNH2
CAS Number:
Molecular Weight:
186.23
Beilstein:
610130
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

분석

97%

형태

powder

mp

103-108 °C (lit.)

SMILES string

Cc1ccc(cc1)S(=O)(=O)NN

InChI

1S/C7H10N2O2S/c1-6-2-4-7(5-3-6)12(10,11)9-8/h2-5,9H,8H2,1H3

InChI key

ICGLPKIVTVWCFT-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

애플리케이션

p-Toluenesulfonyl hydrazide was used as a reagent for the preparation of tosylhydrazones. It was used to prepare dipyrazolo[1,5-a:4′,3′-c]pyridines and 1,2,3-selenadiazole derivatives.

픽토그램

FlameSkull and crossbonesEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 2 - Self-react. D

보충제 위험성

Storage Class Code

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 3

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


시험 성적서(COA)

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문서 라이브러리 방문

Journal of the American Chemical Society, 114, 966-966 (1992)
Mousa Al-Smadi et al.
Molecules (Basel, Switzerland), 13(11), 2740-2749 (2008-11-07)
The commercially available aromatic polyketones 1a-d were utilized for the synthesis of the multi-arm1,2,3-selenadiazole derivatives 3a-d. The preparation starts with the reaction between compounds 1a-d and p-toluenesulfonyl hydrazide to give the corresponding tosylhydrazones 2a-d. Subsequent reaction with selenium dioxide leads
Wolfgang Holzer et al.
Beilstein journal of organic chemistry, 8, 2223-2229 (2013-02-01)
The synthesis of dipyrazolo[1,5-a:4',3'-c]pyridines is described. Easily obtainable 5-alkynylpyrazole-4-carbaldehydes, p-toluenesulfonyl hydrazide, and an aldehyde or ketone containing an α-hydrogen atom were reacted in a silver triflate catalyzed multicomponent reaction affording new tricyclic compounds with a dipyrazolo[1,5-a:4',3'-c]pyridine core. Detailed NMR spectroscopic
Journal of the American Chemical Society, 115, 2473-2473 (1993)
D H Blakey et al.
Toxicology and industrial health, 8(6), 369-376 (1992-11-01)
Toluenesulfonhydrazide (TSH) is a high volume production chemical for which there is relatively little toxicological data. In this study, the mutagenic activity of TSH was determined in the Salmonella/mammalian microsome assay and the in vitro chromosomal aberration assay using Chinese

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