71320

Sodium borohydride

purum p.a., ≥96% (gas-volumetric)

• 동의어(들): Sodium tetrahydridoborate
• Linear Formula: NaBH₄
• CAS Number: 16940-66-2
• Molecular Weight: 37.83
• EC Number: 241-004-4
• MDL number: MFCD00003518
• UNSPSC 코드: 26111700
• PubChem Substance ID: 57652284
• NACRES: NA.22

속성

• grade: purum p.a.
• Quality Level: 200
• 분석: ≥96% (gas-volumetric)
• 양식: powder
• 반응 적합성: reagent type: reductant
• mp: >300 °C (dec.) (lit.)
• 음이온 미량물: chloride (Cl^-): ≤5000 mg/kg; sulfate (SO₄^2-): ≤50 mg/kg
• 양이온 미량물: Ca: ≤50 mg/kg; Cd: ≤50 mg/kg; Co: ≤50 mg/kg; Cu: ≤50 mg/kg; Fe: ≤50 mg/kg; K: ≤1000 mg/kg; Ni: ≤50 mg/kg; Pb: ≤50 mg/kg; Zn: ≤50 mg/kg
• SMILES string: [BH4-].[Na+]
• InChI: 1S/BH4.Na/h1H4;/q-1;+1

설명

일반 설명

Sodium borohydride is considered as a selective reducing agent due to its ability to selectively reduce aldehydes and ketones into their corresponding alcohols in the presence of other functional groups such as nitro, ester, amide, lactone, epoxide, and nitriles that are otherwise susceptible to reduction.[1] It is being considered as a promising candidate for hydrogen storage applications.[2]

애플리케이션

Sodium borohydride may be used as a reductant and hydrogen source for the semi-hydrogenation of alkynes to the corresponding alkenes in the presence of nickel nanoparticles generated in situ from nickel chloride and methanol.[3] It can also be used as a reducing agent for the synthesis of gold nanoparticles from gold chloride.[4]

기타 정보

Reduction of carboxylic acid derivatives [5][6]

안전성 정보

• 픽토그램: GHS02,GHS06,GHS08,GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H260,H301,H314,H360FD
• 예방조치 성명서: P231 + P232 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react 1
• 보충제 위험성: EUH014
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 2
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges