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Merck
모든 사진(3)

주요 문서

A10701

Sigma-Aldrich

Acetophenone

ReagentPlus®, 99%

동의어(들):

Methyl phenyl ketone

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About This Item

Linear Formula:
CH3COC6H5
CAS Number:
Molecular Weight:
120.15
Beilstein:
605842
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.21

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vapor density

4.1 (vs air)

Quality Level

vapor pressure

0.45 mmHg ( 25 °C)
1 mmHg ( 15 °C)

제품 라인

ReagentPlus®

분석

99%

양식

liquid

autoignition temp.

1058 °F

refractive index

n20/D 1.534 (lit.)

bp

202 °C (lit.)

mp

19-20 °C (lit.)

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일반 설명

Acetophenone is an aromatic ketone used in the synthesis of alcohol by catalytic hydrogenation, and also in perfumery.[1][2]

Acetophenone (AP, methyl phenyl ketone) is a common industrial solvent.[3] It can be synthesized from 1-phenylethanol in the presence of PdAu-NPs-TiO2 (titanium dioxide-supported palladium gold bimetallic nanoparticles) hybrid.[4] Its vacuum ultraviolet absorption spectrum shows absorption bands at 196, 191, 179 and 167mμ.[5] AP reacts with α-naphtylphenylsilane in the presence of N-chelate ligands based on chiral oxazolines to undergo hydrosilylation with high enantioselectivity.[6] It can also undergo hydrogenation reaction in the presence of different transition metal catalysts under different conditions.[7][8][9]

애플리케이션

Acetophenone was used to induce peak currents in M71 neurons using voltage clamp.[10] It may be used in the synthesis of N-(1-phenylethyl)formamide, via Leuckart reaction.[11]

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

픽토그램

Exclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point (°F)

179.6 °F - closed cup

Flash Point (°C)

82 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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문서 라이브러리 방문

Hydrogenation of aromatic ketones with Pt-and Sn-modified Pt catalysts
Gerardo S F et al.
Applied Catalysis A: General, 215-223, 269-269 (2004)
Vacuum ultraviolet spectra of styrene, benzaldehyde, acetophenone, and benzonitrile.
Kimura K and Nagakura S.
Theoretica chimica acta, 3(2), 164-173 (1965)
Ultrasonic studies on binary mixtures of some aromatic ketones with acetonitrile at T= 308.15 K
Savitha T et al.
The Journal of Chemical Thermodynamics, 38, 1438-1442 (2006)
Green-chemistry Compatible Approach to TiO2-supported PdAu Bimetallic Nanoparticles for Solvent-free 1-Phenylethanol Oxidation under Mild Conditions.
Chang JB, et al.
Nano-Micro Letters, 7(3), 307-315 (2015)
Photocatalytic reduction of acetophenone in membrane reactors under UV and visible light using TiO2 and Pd/TiO2 catalysts.
Molinari R, et al.
Chemical Engineering Journal, 274, 307-316 (2015)

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