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104094

Sigma-Aldrich

Piperidine

ReagentPlus®, 99%

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Synonym(s):
Hexahydropyridine
Empirical Formula (Hill Notation):
C5H11N
CAS Number:
Molecular Weight:
85.15
Beilstein:
102438
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.21

vapor density

2.94 (vs air)
3 (vs air)

Quality Level

vapor pressure

23 mmHg ( 20 °C)
23 mmHg ( 20 °C)

product line

ReagentPlus®

Assay

99%

impurities

≤0.5% water (Karl Fischer)

refractive index

n20/D 1.452 (lit.)

bp

106 °C (lit.)

mp

−13 °C (lit.)

solubility

organic solvents: soluble(lit.)
water: miscible(lit.)

density

0.862 g/mL at 20 °C (lit.)

SMILES string

C1CCNCC1

InChI

1S/C5H11N/c1-2-4-6-5-3-1/h6H,1-5H2

InChI key

NQRYJNQNLNOLGT-UHFFFAOYSA-N

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1 of 4

This Item
PX12354110278.22299
Piperidine ReagentPlus®, 99%

Sigma-Aldrich

104094

Piperidine

Piperidine

Supelco

PX1235

Piperidine

Piperidine ≥99.5%, purified by redistillation

Sigma-Aldrich

411027

Piperidine

Piperidine for synthesis

Sigma-Aldrich

8.22299

Piperidine

refractive index

n20/D 1.452 (lit.)

refractive index

-

refractive index

n20/D 1.452 (lit.)

refractive index

-

bp

106 °C (lit.)

bp

106 °C/1013 hPa

bp

106 °C (lit.)

bp

106 °C/1013 hPa

mp

−13 °C (lit.)

mp

-10.8 °C

mp

−13 °C (lit.)

mp

-10.8 °C

solubility

organic solvents: soluble(lit.), water: miscible(lit.)

solubility

-

solubility

-

solubility

-

density

0.862 g/mL at 20 °C (lit.)

density

0.86 g/cm3 at 20 °C

density

0.862 g/mL at 20 °C (lit.)

density

0.86 g/cm3 at 20 °C

General description

Piperidine can be prepared either by nickel catalyzed hydrogenation of pyridine or by cobalt catalyzed hydrogenolysis of tetrahydrofurylamine It forms adducts with α,β,γ,δ-tetraphenylporphyriniron(II) and protoporphyriniron(II). Mossbauer spectra of these adducts have been evaluated. It constitutes the skeleton of various alkaloids. Its chemical reactivity has been discussed.

Application

Piperidine may be employed as protective and structure-directing agent in the post synthesis of MCM (Mobil Composition of Matter)-49 zeolites.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

60.8 °F - closed cup

Flash Point(C)

16 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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