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80430

Sigma-Aldrich

Dichlorodimethylsilane

produced by Wacker Chemie AG, Burghausen, Germany, ≥99.0% (GC)

Synonym(s):

Silane M2, DMDCS, Dimethyldichlorosilane

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About This Item

Linear Formula:
(CH3)2SiCl2
CAS Number:
75-78-5
Molecular Weight:
129.06
Beilstein/REAXYS Number:
605287
EC Number:
200-901-0
MDL number:
MFCD00000491
UNSPSC Code:
12352101
PubChem Substance ID:
329768859
NACRES:
NA.22

grade

produced by Wacker Chemie AG, Burghausen, Germany

Quality Level

100

assay

≥99.0% (GC)

form

liquid

refractive index

n20/D 1.404 (lit.)

bp

70 °C (lit.)

mp

−76 °C (lit.)

density

1.07 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(Cl)Cl

InChI

1S/C2H6Cl2Si/c1-5(2,3)4/h1-2H3

InChI key

LIKFHECYJZWXFJ-UHFFFAOYSA-N

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General description

Dichlorodimethylsilane is an organosilicon compound generally used as a protecting group for diols and carbonyl compounds. It is also used as a starting material for the preparation of silicon-based reagents.

Application

Dichlorodimethylsilane can be used:
  • As a silane coupling agent in the synthesis of silica nanoparticles and in their surface modification studies.
  • To prepare polydimethylsiloxane microemulsions by reacting with sodium dodecylpolyoxyethylene sulfate.
  • To prepare a novel heterasumanene where the benzylic carbon atoms of the sumanene are replaced by heteroatom (S, Si) functionalities

Other Notes

prices for bulk quantities on request

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

33.8 °F - closed cup

flash_point_c

1 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ3001
BCCF3092
103112311
BCBS5869V
BCBK0272V

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Zhongyan Lu et al.
American journal of physiology. Regulatory, integrative and comparative physiology, 307(5), R558-R570 (2014-06-13)
Ruminal fermentation products such as short-chain fatty acids (SCFA) and CO2 acutely stimulate urea transport across the ruminal epithelium in vivo, whereas ammonia has inhibitory effects. Uptake and signaling pathways remain obscure. The ruminal expression of SLC14a1 (UT-B) was studied
S C Lung et al.
Chemosphere, 41(12), 1865-1871 (2000-11-04)
The effects of coating materials on polychlorinated biphenyl (PCB) adsorption in aqueous solution were assessed in an attempt to minimize PCB sorption loss during sampling processes. A coating material, which enhances PCB adsorption and allows adsorbed PCBs to be readily
J M Curran et al.
Biomaterials, 32(21), 4753-4760 (2011-04-15)
Material modifications can be used to induce cell responses, in particular-CH(3) and -NH(2) have shown potential in enhancing the ability of a material to support mesenchymal stem cell (MSC) adhesion and differentiation. Currently this process is variable, due to the
Niels P Boks et al.
Microbiology (Reading, England), 154(Pt 10), 3122-3133 (2008-10-04)
Using a parallel-plate flow chamber, the hydrodynamic shear forces to prevent bacterial adhesion (F(prev)) and to detach adhering bacteria (F(det)) were evaluated for hydrophilic glass, hydrophobic, dimethyldichlorosilane (DDS)-coated glass and six different bacterial strains, in order to test the following
K E Healy et al.
Biomaterials, 17(2), 195-208 (1996-01-01)
Materials with spatially resolved chemistries (i.e. patterned surfaces) have been used to guide and organize the position of mammalian cells in vitro. A common theme in guiding the spatial distribution of cells has been the use of patterned alkylsiloxanes, where
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