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Key Documents

Safety Information

213403

Sigma-Aldrich

N-Selectride®

1.0 M in THF

Synonym(s):

Sodium tri-sec-butylborohydride solution

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About This Item

Linear Formula:
NaB[CH(CH3)C2H5]3H
CAS Number:
Molecular Weight:
206.15
MDL number:
UNSPSC Code:
12352001
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

reaction suitability

reagent type: reductant

concentration

1.0 M in THF

density

0.893 g/mL at 25 °C (lit.)

SMILES string

[Na+].CCC(C)[BH-](C(C)CC)C(C)CC

InChI

1S/C12H28B.Na/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-13H,7-9H2,1-6H3;/q-1;+1

InChI key

JUFGMKFPFVIKOY-UHFFFAOYSA-N

Application

  • Reducing agent

Reactant for:
  • Conjugate hydride reduction-initiated tandem cyclization reactions
  • Sereoselective nucleophilic addition reactions

Legal Information

Selectride is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Respiratory system

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

5.0 °F - closed cup

Flash Point(C)

-15 °C - closed cup


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Materials containing Organometallic compounds
Hazardous rank I
1st spontaneously combustible materials and water reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

213403-100ML:4548173116341
213403-BULK:
213403-VAR:
213403-800ML:4548173116358


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