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Safety Information

225924

Sigma-Aldrich

LS-Selectride® solution

1.0 M in THF

Synonym(s):

Lithium trisiamylborohydride solution

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About This Item

Linear Formula:
LiB[CH(CH3)CH(CH3)2]3H
CAS Number:
60217-34-7
Molecular Weight:
232.18
MDL number:
MFCD00011700
UNSPSC Code:
12352001
PubChem Substance ID:
24853533
NACRES:
NA.22

form

liquid

Quality Level

100

reaction suitability

reagent type: reductant

concentration

1.0 M in THF

density

0.903 g/mL at 25 °C

SMILES string

[Li+].CC(C)C(C)[BH-](C(C)C(C)C)C(C)C(C)C

InChI

1S/C15H34B.Li/c1-10(2)13(7)16(14(8)11(3)4)15(9)12(5)6;/h10-16H,1-9H3;/q-1;+1

InChI key

DGIADQRDWIBVOW-UHFFFAOYSA-N

Related Categories

Application

Reactant for:
  • Nucleophilic addition reactions
  • Conjugate reduction-initiated cyclization reactions

Legal Information

Selectride is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

33.8 °F - closed cup

Flash Point(C)

1 °C - closed cup

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Materials containing Organometallic compounds
Hazardous rank I
1st spontaneously combustible materials and water reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

225924-VAR:
225924-100ML:4548173119434
225924-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBK5304
SHBK5027
SHBJ9773
SHBJ5085
SHBH5048V

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