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221651

Sigma-Aldrich

Aluminum-nickel catalyst

Al-Ni 50:50 wt. %

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About This Item

Empirical Formula (Hill Notation):
AlNi
CAS Number:
12635-27-7
Molecular Weight:
85.67
MDL number:
MFCD00167392
UNSPSC Code:
12352202
PubChem Substance ID:
24853255
NACRES:
NA.22

composition

Al-Ni, 50:50 wt. %

Quality Level

100

reaction suitability

core: nickel
reagent type: catalyst

manufacturer/tradename

W.R. Grace and Co. Raney®

density

3.46 g/mL at 25 °C (lit.)

SMILES string

[Al].[Ni]

InChI

1S/Al.Ni

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

Application

Catalyst for:
  • Reduction reactions
  • Reductive dehalogenation and ring saturation reactions

Used for:
  • Preparation of aluminum oxy-hydrate supported NiAl skeleton catalyst for hydrogenation reactions
Raney-type alloy for the preparation of Raney® Nickel catalyst. ,

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.

Signal Word

Danger

Hazard Statements

H228,H261,H317,H351

Hazard Classifications

Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - Water-react 2

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

221651-VAR:
221651-500G:
221651-BULK:
221651-100G:
221651-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV9064
MKBN7634V
MKBB7662
08323MW
05919TV

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Sandesh S Raut et al.
Chemosphere, 250, 126298-126298 (2020-04-03)
Chlorophenol (CP) is considered as environmentally hazardous material due to its acute toxicity, persistent nature and strong bioaccumulation. The dechlorination of 4-CP was investigated by using various catalysts such as bimetallic (Fe0/Cu0, Al0/Fe0), Pd/C, Raney Ni and Fe0 at room
Jaeyong Park et al.
ChemSusChem, 12(8), 1743-1762 (2019-02-01)
Highly dispersed, core-shell Ni@Al2 O3 on activated carbon (AC) catalysts were prepared to develop an effective, external-hydrogen-free fractionation process for various types of lignocellulosic biomass. In a mixture of formic acid, ethanol, and water at 190 °C, the conversion of oak

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Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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