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72240

Sigma-Aldrich

Aluminum-nickel alloy

purum, 50% Al basis, 50% Ni basis

Synonym(s):

Nickel-aluminum alloy, Raney®-Nickel alloy

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About This Item

CAS Number:
12635-27-7
MDL number:
MFCD00167392
UNSPSC Code:
12161600
PubChem Substance ID:
329763924
NACRES:
NA.22

Quality Level

100

grade

purum

form

powder

composition

Al, 50%
Ni, 50%

reaction suitability

core: nickel
reagent type: catalyst

SMILES string

[Al].[Ni]

InChI

1S/Al.Ni

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

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Application

Aluminum-nickel alloy can be used:
  • For the reduction of nitriles, nitro compounds and oximes to primary amines.
  • For the conversion of carbonyl compounds to hydrocarbons.
  • As a reducing agent to convert Ar-X derivatives to Ar-H compounds.
  • For the synthesis of Raney nickel catalyst to be used as an alkylating agent.
  • To synthesize non-pyrophoric Ni catalyst by alkali leaching.
  • For the synthesis of alloyed skeletal Ni catalysts.

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.

replaced by

Product No.
Description
Pricing

Signal Word

Danger

Hazard Statements

H228,H261,H317,H351

Hazard Classifications

Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - Water-react 2

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 2: Flammable solids
Metal powder
Hazardous rank II
1st combustible solid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

72240-100G:4548173945910
72240-BULK:
72240-VAR:
72240-500G:4548173945927

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Certificates of Analysis (COA)

Lot/Batch Number
STBL4833
STBL4241
STBL2362
STBL0821
STBK7565

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An environmentally benign and catalytically efficient non-pyrophoric Ni catalyst for aqueous-phase reforming of ethylene glycol.
Zhu LJ, et al.
Green Chemistry, 10(12), 1323-1330 (2008)
Highly selective hydrogenation of C?C double bond in unsaturated carbonyl compounds over NiC catalyst.
Mahata N, et al.
Chemical Engineering Journal, 188(4), 155-159 (2012)
Steam reforming of ethanol over skeletal Ni-based catalysts: A temperature programmed desorption and kinetic study
Zhang C, et al.
AIChE Journal, 60(2), 635-644 (2014)
Reinvestigating Raney nickel mediated selective alkylation of amines with alcohols via hydrogen autotransfer methodology.
Mehta A, et al.
Applied Catalysis A: General, 478(4), 241-251 (2014)
Nickel-aluminum alloy as a reducing agent.
Keefer LK and Lunn G
Chemical Reviews, 89(3), 459-502 (1989)
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Self-Propagating Reactions Induced by Mechanical Alloying

An article concerning self-propagating reactions induced by mechanical alloying, presented by Sigma-Aldrich.com.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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