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Safety Information

227730

Sigma-Aldrich

Silver hexafluoroantimonate(V)

98%

Synonym(s):

Silver hexafluoroantimony, Silver hexafluorostiboranuide

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About This Item

Linear Formula:
AgSbF6
CAS Number:
26042-64-8
Molecular Weight:
343.62
EC Number:
247-429-1
MDL number:
MFCD00003401
UNSPSC Code:
12352302
PubChem Substance ID:
24853650
NACRES:
NA.23

Quality Level

100

Assay

98%

form

powder

reaction suitability

reagent type: catalyst
core: silver

SMILES string

[Ag+].F[Sb-](F)(F)(F)(F)F

InChI

1S/Ag.6FH.Sb/h;6*1H;/q+1;;;;;;;+5/p-6

InChI key

GSXFODUDOAXUBF-UHFFFAOYSA-H

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Application

Generates stable cation radical salts and is used as an acidic catalyst in epoxide opening reactions and sulfenylation reactions. Used to prepare silver 3,3′-dicyanodiphenylacetylene coordination networks for study of the effect of ligands on network structure toward the goal of engineering novel materials.

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302 + H332,H411

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

227730-BULK:
227730-5G:4548173119991
227730-VAR:
227730-25G:4548173119984
227730-1G:4548173119977

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT4952
MKCS8090
MKCR7517
MKCQ1923
MKCP5655

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Development of a Nazarov cyclization/Wagner-Meerwein rearrangement sequence for the stereoselective synthesis of spirocycles.
Jie Huang et al.
Journal of the American Chemical Society, 129(26), 8060-8061 (2007-06-09)
Chemistry Letters (Jpn), 1901-1901 (1992)
The Journal of Organic Chemistry, 57, 6178-6178 (1992)
Chemistry Letters (Jpn), 1-1 (1993)
Keith A. Hirsch et al.
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar

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