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213233

Sigma-Aldrich

Lithium chloride

ReagentPlus®, 99%

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About This Item

Linear Formula:
LiCl
CAS Number:
7447-41-8
Molecular Weight:
42.39
EC Number:
231-212-3
MDL number:
MFCD00011078
UNSPSC Code:
12352302
PubChem Substance ID:
329752142
NACRES:
NA.21

Quality Level

100

product line

ReagentPlus®

Assay

99%

form

powder, crystals or granules

pH

6

mp

605 °C (lit.)

storage temp.

room temp

SMILES string

[Li+].[Cl-]

InChI

1S/ClH.Li/h1H;/q;+1/p-1

InChI key

KWGKDLIKAYFUFQ-UHFFFAOYSA-M

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Application

Lithium chloride can be used as a catalyst in the:
  • Mukaiyama-type Mannich reaction of methylsilyl enol ethers with arylaldimines to synthesize β-amino carbonyl compounds.
  • Microwave-irradiated chemo- and regioselective demethylation of aryl methyl ethers.
  • Aza-Michael addition reaction of pyrazoles to α,β-unsaturated imides.

Other Notes

Go to Redi-Dri™ Product Listing 793620

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

213233-10KG:
213233-2KG:
213233-BULK:
213233-VAR:
213233-VAR-D:
213233-100G:
213233-12KG:
213233-500G:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Daniel I Perez et al.
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Wnt signaling is one of the earliest and most highly conserved regulatory pathways for the establishment of the body axes during regeneration and early development. In regeneration, body axes determination occurs independently of tissue rearrangement and early developmental cues. Modulation
A Abu-Baker et al.
Cell death & disease, 4, e821-e821 (2013-10-05)
Expansion of polyalanine tracts causes at least nine inherited human diseases. Among these, a polyalanine tract expansion in the poly (A)-binding protein nuclear 1 (expPABPN1) causes oculopharyngeal muscular dystrophy (OPMD). So far, there is no treatment for OPMD patients. Developing
Gry Hulsart Billström et al.
Injury, 44 Suppl 1, S28-S33 (2013-02-13)
Scaffolds are extensively used in surgery to replace missing bone and to achieve bony union and fusion. An ideal scaffold should not only maintain, induce, and restore biological functions where cells, extracellular matrix, and growth factors are needed, but also
A M Petrosyan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 105, 623-625 (2013-02-07)
We argue that the recently reported crystals "L-threonine formate" as well as "L-alanine lithium chloride" and "bis L-alanine lithium chloride" actually are the well-known crystals L-threonine and L-alanine, respectively.
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