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Safety Information

270547

Sigma-Aldrich

N,N-Dimethylformamide

suitable for HPLC, ≥99.9%

Synonym(s):

DMF, NSC 5356

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About This Item

Linear Formula:
HCON(CH3)2
CAS Number:
68-12-2
Molecular Weight:
73.09
Beilstein:
605365
EC Number:
200-679-5
MDL number:
MFCD00003284
UNSPSC Code:
12190000
PubChem Substance ID:
329752951
NACRES:
NA.21
Assay:
≥99.9%
technique(s):
HPLC: suitable
application(s):
food and beverages
bp:
153 °C (lit.)
vapor pressure:
2.7 mmHg ( 20 °C)

vapor density

2.5 (vs air)

Quality Level

100

vapor pressure

2.7 mmHg ( 20 °C)

Assay

≥99.9%

form

liquid

autoignition temp.

833 °F

purified by

glass distillation

expl. lim.

15.2 %

technique(s)

HPLC: suitable

impurities

≤0.030% water

evapn. residue

<0.0005%

refractive index

n20/D 1.430 (lit.)

pH

6.7

bp

153 °C (lit.)

mp

−61 °C (lit.)

density

0.944 g/mL (lit.)

λ

H2O reference

UV absorption

λ: 270 nm Amax: 1.00
λ: 275 nm Amax: 0.30
λ: 295 nm Amax: 0.10
λ: 310 nm Amax: 0.05
λ: 340-400 nm Amax: 0.01

application(s)

food and beverages

SMILES string

[H]C(=O)N(C)C

InChI

1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3

InChI key

ZMXDDKWLCZADIW-UHFFFAOYSA-N

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Application

Solvent for many hydrophobic organic compounds.

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Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

135.5 °F - closed cup

Flash Point(C)

57.5 °C - closed cup

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water soluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

270547-4L-PW:
270547-4X2.5L:
270547-BULK:
270547-2.5L:
270547-4L:
270547-1L:4548173127743
270547-500ML:
270547-4X4L:4548173127774
270547-VAR:
270547-6X1L:4548173127781
270547-2L:4548173127750
270547-200L:
270547-100ML:4548173127729
270547-4X2L:4548173127767
270547-10L:4548173127736

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Certificates of Analysis (COA)

Lot/Batch Number
STBL4656
STBL4655
STBL4449
STBL4299
STBL4289

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W P Inskeep et al.
Plant physiology, 77(2), 483-485 (1985-02-01)
We found inconsistencies in the commonly used data for chlorophyll analysis in 80% acetone. Recently developed extinction coefficients for chlorophyll b in N,N-dimethylformamide (DMF) based on values from 80% acetone are low as a result of these inconsistencies. We determined
Leonard Blaschek et al.
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