추천 제품
Grade
reagent grade
Quality Level
분석
97%
형태
solid
bp
125 °C (lit.)
mp
86-89 °C (lit.)
SMILES string
CC(C)(C)[Si](C)(C)Cl
InChI
1S/C6H15ClSi/c1-6(2,3)8(4,5)7/h1-5H3
InChI key
BCNZYOJHNLTNEZ-UHFFFAOYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
애플리케이션
tert-Butyldimethylsilyl chloride (TBDMSCl) is an organosilicon compound that can be used as a versatile protecting reagent for alcohols, amines, amides, and various carboxylic acids. It is also used in the preparation of isoxazoline N-oxides from α-bromonitroalkanes and olefins. TBDMSCl is used as a precursor that forms a silicon substrate for Ag/ZnO/graphene-based nanocomposites to form effective photocatalytic system for hydrogen production.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Aquatic Chronic 2 - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1A
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
WGK 2
Flash Point (°F)
71.6 °F - closed cup
Flash Point (°C)
22 °C - closed cup
이미 열람한 고객
New approach for the synthesis of isoxazoline-N-oxides
Organic Letters, 5(25) (2003)
Protective Groups in Organic Synthesis (1991)
Organic letters, 5(25), 4907-4909 (2003-12-05)
A strategy for the synthesis of isoxazoline-N-oxides (cyclic five-membered nitronates) from primary nitro compounds and olefins is described. The key step of the process involves 1,3-dipolar cycloaddition of corresponding 1-bromosilyl nitronates with alkenes. [reaction: see text]
Handbook of Reagents for Organic Synthesis, Activating Agents and Protecting Groups Handbook of Reagents for Organic Synthesis, Activating Agents and Protecting Groups, 1999
Bulletin of the Chemical Society of Japan, 78(5), 917-928 (2005)
Journal of the Chemical Society. Chemical Communications, 125-125 (1993)
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