241911

Tungsten(VI) chloride

≥99.9% trace metals basis

• 동의어(들): Tungsten hexachloride
• Linear Formula: WCl₆
• CAS Number: 13283-01-7
• Molecular Weight: 396.56
• EC Number: 236-293-9
• MDL number: MFCD00011463
• UNSPSC 코드: 12352302
• PubChem Substance ID: 24854501
• NACRES: NA.23

속성

• vapor pressure: 43 mmHg ( 215 °C)
• Quality Level: 100
• 분석: ≥99.9% trace metals basis
• 양식: powder
• 반응 적합성: reagent type: catalyst; core: tungsten
• 불순물: ≤1000.0 ppm Trace Metal Analysis
• bp: 347 °C (lit.)
• mp: 275 °C (lit.)
• density: 3.52 g/mL at 25 °C (lit.)
• SMILES string: Cl[W](Cl)(Cl)(Cl)(Cl)Cl

설명

일반 설명

Tungsten(VI) chloride is a highly reactive crystalline solid commonly used in the field of catalysis, perovskite solar cells, and light-emitting devices. It is a diamagnetic solid. However, it can be highly corrosive and have strong oxidizing effects.

애플리케이션

Tungsten(VI) chloride can be used:

• As a starting material to synthesize tungsten nanoparticles[1] and Mo-doped urchin-like W₁₈O₄₉ Nanostructure using the hydrothermal method. The Mo-W₁₈O₄₉ electrocatalyst exhibited excellent electrocatalytic activity toward Hydrogen Evolution Reaction (HER).[2] By doping Mo species into defect-rich W₁₈O₄₉ ultrathin nanowires, it has also been demonstrated to be an excellent candidate for photocatalytic N₂ fixation to ammonia.[3]
• To synthesize crystalline mesoporous WO₃ with 11 nm pore size utilizing a high-molecular-weight amphiphilic block copolymer as the structure-directing agent. The materials performed admirably in terms of H₂S gas sensing.[4]
• To fabricate Tungsten disulfide and WS₂/reduced graphene oxide (WS₂/rGO) nanosheets by hydrothermal synthesis. The WS₂/rGO nanosheets showed exceptional electrocatalytic activity for the hydrogen evolution reaction.
• To produce the WS₂-nanoflowers@rGO and nitrogen-doped carbon spheres@WS₂ composite as an anode material for enhanced electrode performance in lithium-ion batteries.[5]
• As a dopant to fabricate TiO₂ compact layers for perovskite solar cells with enhanced performance.[6]
• As a catalyst to prepare self-healing epoxy composites with microcapsules.[7]
• As a catalyst for transamidation of tertiary alkyl amides.[8]

안전성 정보

• 픽토그램: GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H314,H335,H412
• 예방조치 성명서: P260 - P271 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges