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252913

Sigma-Aldrich

5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride

≥95% (HPLC)

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Empirical Formula (Hill Notation):
C44H8ClF20FeN4
CAS Number:
Molecular Weight:
1063.83
MDL number:
PubChem Substance ID:
NACRES:
NA.23

assay

≥95% (HPLC)

form

powder

reaction suitability

reagent type: catalyst
core: iron

λmax

415 nm
498 nm (2nd)

SMILES string

Fc1c(F)c(F)c(c(F)c1F)-c2c3ccc(n3)c(-c4c(F)c(F)c(F)c(F)c4F)c5ccc6c(-c7c(F)c(F)c(F)c(F)c7F)c8ccc(n8)c(-c9c(F)c(F)c(F)c(F)c9F)c%10ccc2n%10[Fe](Cl)n56

InChI

1S/C44H8F20N4.ClH.Fe/c45-25-21(26(46)34(54)41(61)33(25)53)17-9-1-2-10(65-9)18(22-27(47)35(55)42(62)36(56)28(22)48)12-5-6-14(67-12)20(24-31(51)39(59)44(64)40(60)32(24)52)16-8-7-15(68-16)19(13-4-3-11(17)66-13)23-29(49)37(57)43(63)38(58)30(23)50;;/h1-8H;1H;/q-2;;+3/p-1/b17-9+,17-11+,18-10+,18-12+,19-13+,19-15+,20-14+,20-16+;;

InChI key

RVNJZXLLVARDGN-VTVSBRCESA-M

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This Item
247367259071252921
form

powder

form

crystalline powder

form

-

form

solid

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

-

λmax

415 nm, 498 nm (2nd)

λmax

415 nm

λmax

418 nm

λmax

416 nm, 507 nm (2nd)

reaction suitability

reagent type: catalyst
core: iron

reaction suitability

-

reaction suitability

-

reaction suitability

-

Application

Catalyst for epoxidations with peroxides, oxidative decarbonylations, and aliphatic hydroxylations.

Features and Benefits

Catalyst for epoxidations with peroxides, oxidative decarbonylations, and aliphatic hydroxylations.
Preferred catalyst in catalytic oxygenation reactions.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Tetrahedron Letters, 33, 4949-4949 (1992)
Journal of the American Chemical Society, 114, 1308-1308 (1992)
Journal of the American Chemical Society, 115, 2775-2775 (1993)

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