- Phosphazene base-catalyzed condensation of trimethylsilylacetate with carbonyl compounds.
Phosphazene base-catalyzed condensation of trimethylsilylacetate with carbonyl compounds.
Chemical communications (Cambridge, England) (2006-07-21)
Koji Kobayashi, Masahiro Ueno, Yoshinori Kondo
PMID16855708
要旨
The t-Bu-P4 base was found to be an excellent catalyst for the condensation of trimethylsilylacetate or trimethylacetonitrile with carbonyl compounds to form functionalized alkenes and beta-enaminoesters were also synthesized by the condensation with formanilides.