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900693

Sigma-Aldrich

9-Mesityl-1,3,6,8-tetramethoxy-10-phenylacridin-10-ium tetrafluoroborate

95%

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About This Item

Empirical Formula (Hill Notation):
C32H32NO4BF4
CAS Number:
Molecular Weight:
581.41
UNSPSC Code:
12161600
NACRES:
NA.22

Quality Level

Assay

95%

form

powder or crystals

reaction suitability

core: acridinium
reagent type: catalyst
reaction type: Photocatalysis

photocatalyst activation

450 nm

SMILES string

CC1=CC(C)=CC(C)=C1C2=C(C(OC)=CC(OC)=C3)C3=[N+](C4=CC=CC=C4)C5=CC(OC)=CC(OC)=C52.FB(F)F.[F-]

Application

Robust acridinium-based photocatalyst reported by Nicewicz and coworkers as an alternative to transition-metal-based photocatalysts with higher chemical stability and attenuated redox potential.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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The Nicewicz lab is focused on the discovery of new and powerful reaction methodologies that proceed via the intermediacy of highly reactive cation radical species. Included in these transformations are anti-Markovnikov selective additions of amines, alcohols, carboxylic acids, amides and mineral acids to alkenes.

Photoredox catalysis utilizes photocatalysts in the presence of visible light to form an array of synthetic transformations including, but not limited to, cross-coupling, C-H functionalization, alkene and arene functionalization, and trifluoromethylation.

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