900421

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate

≥95%, powder or crystals

• Synonym(s): 3,6-Bis(1,1-dimethylethyl)-10-phenyl-9-(2,4,6-trimethylphenyl)-acridinium tetrafluoroborate, 3,6-Di-tert-butyl-9-(2,4,6-trimethylphenyl)-10-phenylacridinium tetrafluoroborate
• Empirical Formula (Hill Notation): C₃₆H₄₀BF₄N
• CAS Number: 1810004-87-5
• Molecular Weight: 573.51
• MDL number: MFCD31381908
• UNSPSC Code: 12352005
• NACRES: NA.22

Properties

• Product Name: 9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate, ≥95%
• Quality Segment: 100
• assay: ≥95%
• form: powder or crystals
• reaction suitability: core: acridinium, reagent type: catalyst; reaction type: Photocatalysis
• mp: 277.2 °C
• photocatalyst activation: 455 nm
• SMILES string: [F-][B+3]([F-])([F-])[F-].C=1C=CC(=CC1)[N+]=2C=3C=C(C=CC3C(=C4C=CC(=CC42)C(C)(C)C)C=5C(=CC(=CC5C)C)C)C(C)(C)C
• InChI: InChI=1S/C36H40N.BF4/c1-23-19-24(2)33(25(3)20-23)34-29-17-15-26(35(4,5)6)21-31(29)37(28-13-11-10-12-14-28)32-22-27(36(7,8)9)16-18-30(32)34;2-1(3,4)5/h10-22H,1-9H3;/q+1;-1
• InChI key: YUNSHKYOOCWQRB-UHFFFAOYSA-N

Description

Application

When employed with TEMPO, this acridinium photocatalyst promotes the site-selective amination of a variety of simple and complex aromatics with heteroaromatic azoles. When ammonium carbamate is used as the amine, anilines can be achieved directly.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate is an acridium-based photocatalyst that can be an alternative to transition-metal-based photocatalysts due to its higher chemical stability and attenuated redox potential.

Other Notes

Site-selective arene C-H amination via photoredox catalysis

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable