214000

TEMPO

98%

• 동의어(들): 2,2,6,6-Tetramethylpiperidine 1-oxyl, 2,2,6,6-Tetramethyl-1-piperidinyloxy, free radical, TEMPO
• 실험식(Hill 표기법): C₉H₁₈NO
• CAS Number: 2564-83-2
• Molecular Weight: 156.25
• Beilstein: 1422418
• EC Number: 219-888-8
• MDL number: MFCD00009599
• UNSPSC 코드: 12352119
• PubChem Substance ID: 24852819
• NACRES: NA.22

속성

• Quality Level: 200
• 분석: 98%
• 형태: solid
• 반응 적합성: reagent type: oxidant
• 환경친화적 대안 제품 특성: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 36-38 °C (lit.)
• 환경친화적 대안 카테고리: Aligned,
• 저장 온도: 2-8°C
• SMILES string: CC1(C)CCCC(C)(C)N1[O]
• InChI: 1S/C9H18NO/c1-8(2)6-5-7-9(3,4)10(8)11/h5-7H2,1-4H3
• InChI key: QYTDEUPAUMOIOP-UHFFFAOYSA-N

설명

일반 설명

TEMPO (2,2,6,6-Tetramethylpiperidin-1-oxyl) is a stable free radical commonly used as an oxidizing agent in organic synthesis. Copper/TEMPO has been utilized in the catalytic oxidation of primary alcohols to aldehydes.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

애플리케이션

TEMPO can be used:

• As a catalytic oxidant for copper-catalyzed, greener oxidation of alcohols under aerobic conditions.
• As a catalytic oxidant in the iodobenzene diacetae oxidation of nerol to neral.
• For trapping the styrenyl radical generated from benzoyl peroxide during nitroxide-mediated radical polymerization of styrene.
• In the carboxylation of water-resistant nanofibrillated cellulose (NFC) films.

Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air

안전성 정보

• 픽토그램: GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H314,H412
• 예방조치 성명서: P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 2
• Flash Point (°F): 152.6 °F - closed cup
• Flash Point (°C): 67 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges