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일반 설명
Triethylamine trihydrofluoride (TREAT-HF) is a mild and selective reagent for the fluorination of a wide variety of compounds.
애플리케이션
Mild and selective reagent that has been used in the fluorination of a wide variety of compounds. For a review, see Aldrichimica Acta.
TREAT-HF can be used in the synthesis of:
- Vicinal difluorides from epoxides.
- 3-fluoroazetidines.
- 9-(2,3-dideoxy-2-fluoro-β-d-threo-pentofuranosyl)adenine (FddA).
- Multivicinal hexafluoroalkanes.
- Aminomethylated 4-fluoropiperidines and 3-fluoropyrrolidines.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1A
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point (°F)
190.4 °F - closed cup
Flash Point (°C)
88 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Anders Foller Füchtbauer et al.
Scientific reports, 7(1), 2393-2393 (2017-05-26)
The bright fluorescent cytosine analogue tC
Synthesis and structure of stereoisomeric multivicinal hexafluoroalkanes
Hunter L, et al.
Angewandte Chemie (International ed. in English), 48(30), 5457-5460 (2009)
Effect of Partially Fluorinated N-Alkyl-Substituted Piperidine-2-carboxamides on Pharmacologically Relevant Properties
Vorberg R, et al.
ChemMedChem, 11(19), 2216-2239 (2016)
Héctor Aguilar-Bolados et al.
Journal of colloid and interface science, 524, 219-226 (2018-04-15)
The fluorination of two types of graphene oxides conducted by an easy and scalable deoxyfluorination reaction is reported. This reaction was carried out using diethylaminodifluorosulfinium tetrafluoroborate, a stable compound and an efficient reagent for replacing oxygenated functional groups of graphene
Saira Ashraf et al.
RNA (New York, N.Y.), 23(12), 1927-1935 (2017-09-29)
Folding properties differ markedly between kink-turns (k-turns) that have different biological functions. While ribosomal and riboswitch k-turns generally fold into their kinked conformation on addition of metal ions, box C/D snoRNP k-turns remain completely unfolded under these conditions, although they
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