386529
Chlorotrimethylsilane
purified by redistillation, ≥99%
동의어(들):
TMSCl, TMCS, Trimethylchlorosilane, Trimethylsilyl chloride
About This Item
추천 제품
vapor density
3.7 (vs air)
Quality Level
vapor pressure
100 mmHg ( 25 °C)
분석
≥99%
양식
liquid
autoignition temp.
752 °F
정제법
glass distillation
redistillation
expl. lim.
6.4 %
불순물
<0.1% dichlorodimethylsilane
refractive index
n20/D 1.387 (lit.)
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일반 설명
애플리케이션
- A reagent to protect alcohol and amine groups via the formation of trimethylsilyl ethers and trimethylsilyl amines.[2][3]
- A catalyst for the preparation of 1,3-diphenyl-2-propenone derivatives (chalcones) as antimicrobial agents.[3]
- A trapping agent for the anions generated during acyloin condensation reaction.[4]
- A better alternative catalyst to the toxic mercuric chloride for the activation of samarium (Sm) during the cyclopropanation of both allylic and α-allenic alcohols.[5]
- A catalyst in the transesterification of triglycerides with alcohols to form fatty acid alkyl esters.[6]
- A reagent along with lithium bromide for the conversion of alcohols to the corresponding bromides.[7]
- A reagent in Fischer glycosidation.[8]
- A source of acid catalyst in the reductive benzylation reaction using benzaldehyde and Et3SiH.[9]
- A reagent to synthesize sodium trimethylsilanethiolate (Me3SiSNa) by reacting with sodium sulfide, which is an odorless alternative method of synthesizing Me3SiSNa from foul-smelling bis(trimethylsilyl)sulfide and sodium methoxide.[10]
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A
보충제 위험성
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point (°F)
-18.4 °F - closed cup
Flash Point (°C)
-28 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles
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