M9653

Methoxyacetyl chloride

97%

• 동의어(들): 2-methoxyacetyl chloride, Methoxyacetic acid chloride
• Linear Formula: CH₃OCH₂COCl
• CAS Number: 38870-89-2
• Molecular Weight: 108.52
• Beilstein: 1740244
• EC Number: 254-169-2
• MDL number: MFCD00000728
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24897347
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 양식: liquid
• refractive index: n20/D 1.419 (lit.)
• bp: 112-113 °C (lit.)
• density: 1.187 g/mL at 25 °C (lit.)
• 저장 온도: 2-8°C
• SMILES string: COCC(Cl)=O
• InChI: 1S/C3H5ClO2/c1-6-2-3(4)5/h2H2,1H3
• InChI key: JJKWHOSQTYYFAE-UHFFFAOYSA-N

설명

애플리케이션

Methoxyacetyl chloride can be used for methoxyacetylation of:

• Bilocularin A to synthesize 8-Methoxyacetoxybilocularin A.[1]
• Substituted and unsubstituted benzamides to synthesize N-(2-methoxyacetyl)-benzamides.[2]

It can also be used for the synthesis of β-lactams by reacting with imines.[3][4] and in the post-synthetic modification of the metal-organic framework (MOF), MIL-101, to synthesize a catalyst for cycloaddition reaction of CO₂ with propylene oxide.[5]

안전성 정보

• 픽토그램: GHS02,GHS06,GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H226,H314,H331,H335
• 예방조치 성명서: P210 - P233 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): 82.4 °F
• Flash Point (°C): 28 °C
• 개인 보호 장비: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter