콘텐츠로 건너뛰기
Merck
  • Catalytic conversion of 1,2-dichlorobenzene using V2O5/TiO2 catalysts by a thermal decomposition process.

Catalytic conversion of 1,2-dichlorobenzene using V2O5/TiO2 catalysts by a thermal decomposition process.

Chemosphere (2009-03-10)
Sungmin Chin, Jongsoo Jurng, Jae-Heon Lee, Seung-Jae Moon
초록

This study examined the catalytic oxidation of 1,2-dichlorobenzene on V(2)O(5)/TiO(2) nanoparticles. The V(2)O(5)/TiO(2) nanoparticles were synthesized by the thermal decomposition of vanadium oxytripropoxide and titanium tetraisopropoxide. The effects of the synthesis conditions, such as the synthesis temperature and precursor heating temperature, were investigated. The specific surface areas of V(2)O(5)/TiO(2) nanoparticles increased with increasing synthesis temperature and decreasing precursor heating temperature. The catalytic oxidation rate of the V(2)O(5)/TiO(2) catalyst formed by thermal decomposition process at a catalytic reaction temperature of 150 and 200 degrees C was 46% and 95%, respectively. As a result, it was concluded that the V(2)O(5)/TiO(2) catalysts synthesized by a thermal decomposition process showed good performance for 1,2-DCB decomposition at a lower temperature.

MATERIALS
제품 번호
브랜드
제품 설명

Supelco
1,2-Dichlorobenzene, PESTANAL®, analytical standard
Sigma-Aldrich
1,2-Dichlorobenzene, anhydrous, 99%
Sigma-Aldrich
1,2-Dichlorobenzene, ReagentPlus®, 99%
Sigma-Aldrich
1,2-Dichlorobenzene, suitable for HPLC, 99%
Sigma-Aldrich
1,2-Dichlorobenzene solution, NMR reference standard, 5% in acetone-d6 (99.9 atom % D), NMR tube size 5 mm × 8 in.