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  • Prussian blue caged in spongiform adsorbents using diatomite and carbon nanotubes for elimination of cesium.

Prussian blue caged in spongiform adsorbents using diatomite and carbon nanotubes for elimination of cesium.

Journal of hazardous materials (2012-04-03)
Baiyang Hu, Bunshi Fugetsu, Hongwen Yu, Yoshiteru Abe
초록

We developed a spongiform adsorbent that contains Prussian blue, which showed a high capacity for eliminating cesium. An in situ synthesizing approach was used to synthesize Prussian blue inside diatomite cavities. Highly dispersed carbon nanotubes (CNTs) were used to form CNT networks that coated the diatomite to seal in the Prussian blue particles. These ternary (CNT/diatomite/Prussian-blue) composites were mixed with polyurethane (PU) prepolymers to produce a quaternary (PU/CNT/diatomite/Prussian-blue), spongiform adsorbent with an in situ foaming procedure. Prussian blue was permanently immobilized in the cell walls of the spongiform matrix and preferentially adsorbed cesium with a theoretical capacity of 167 mg/g cesium. Cesium was absorbed primarily by an ion-exchange mechanism, and the absorption was accomplished by self-uptake of radioactive water by the quaternary spongiform adsorbent.

MATERIALS
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