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M55909

Sigma-Aldrich

Methyl methacrylate

contains ≤30 ppm MEHQ as inhibitor, 99%

Synonym(s):
Methacrylic acid methyl ester, Methyl 2-methylprop-2-enoate, Methyl 2-methylpropenoate
Linear Formula:
CH2=C(CH3)COOCH3
CAS Number:
Molecular Weight:
100.12
Beilstein:
605459
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

vapor density

3.5 (vs air)

Quality Level

vapor pressure

29 mmHg ( 20 °C)

Assay

99%

autoignition temp.

815 °F

contains

≤30 ppm MEHQ as inhibitor

expl. lim.

12.5 %

refractive index

n20/D 1.414 (lit.)

bp

100 °C (lit.)

mp

−48 °C (lit.)

density

0.936 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

COC(=O)C(C)=C

InChI

1S/C5H8O2/c1-4(2)5(6)7-3/h1H2,2-3H3

InChI key

VVQNEPGJFQJSBK-UHFFFAOYSA-N

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This Item
W400201234893151238
Methyl methacrylate contains ≤30 ppm MEHQ as inhibitor, 99%

Sigma-Aldrich

M55909

Methyl methacrylate

Methyl methacrylate 99%, stabilized

Sigma-Aldrich

W400201

Methyl methacrylate

Ethyl methacrylate contains 15-20 ppm monomethyl ether hydroquinone as inhibitor, 99%

Sigma-Aldrich

234893

Ethyl methacrylate

Glycidyl methacrylate 97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor

Sigma-Aldrich

151238

Glycidyl methacrylate

assay

99%

assay

99%

assay

99%

assay

97%

contains

≤30 ppm MEHQ as inhibitor

contains

hydroquinone monomethyl ether as stabilizer

contains

15-20 ppm monomethyl ether hydroquinone as inhibitor

contains

100 ppm monomethyl ether hydroquinone as inhibitor

refractive index

n20/D 1.414 (lit.)

refractive index

n20/D 1.414 (lit.)

refractive index

n20/D 1.413 (lit.)

refractive index

n20/D 1.449 (lit.)

bp

100 °C (lit.)

bp

100 °C (lit.)

bp

118-119 °C (lit.)

bp

189 °C (lit.)

mp

−48 °C (lit.)

mp

−48 °C (lit.)

mp

-

mp

-

General description

Methyl methacrylate is an organic compound derived from methacrylic acid, which belongs to the class of acrylic acids. It is a highly reactive monomer and is commonly used in the production of polymers, specifically poly(methyl methacrylate) (PMMA). It is also used to synthesize various poly(methyl methacrylate) (PMMA) materials, which are transparent, hard, and durable. These materials have a wide range of applications, including optical lenses, optoelectronic devices, automotive parts, and medical devices. It is also a good solvent for several polymers and provides high adhesive strength.

Application

Methyl methacrylate can be used as a monomer to prepare:
  • Lanthanide-complex grafted poly(methyl methacrylate-co-maleic anhydride) copolymer. These luminescent polymers exhibit high thermal stability and can be used as luminous layers for optoelectronic devices.
  • Poly (methyl methacrylate) (PMMA), is a common material used in the production of lenses for concentrating photovoltaic (CPV) modules.
  • Polymethyl methacrylate, methyl methacrylate crosspolymer, and methyl methacrylate/glycol dimethacrylate crosspolymers. These polymers are used in cosmetic surgery, dentistry, and joint replacement.
  • Poly (methyl methacrylate) (PMMA)-based personalized medical devices.
Methyl methacrylate can be used as a monomer to prepare:
  • Interpenetrating methyl methacrylate-based polymeric networks with enhanced thermal and mechanical properties.
  • Poly(methyl methacrylate-co-hydroxyethyl methacrylate) (PMMA-co-PHEMA) copolymers by emulsion copolymerization. These copolymers form thermooxidatively stable and ductile films.
  • Poly(methyl methacrylate) nanoparticles through differential microemulsion polymerization.

Pictograms

FlameExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

50.0 °F - closed cup

Flash Point(C)

10 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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705578-5MG-PW

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MMYOMAG-74K-13

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J Ratliff et al.
Spine, 26(13), E300-E302 (2001-07-18)
Case report and literature review. Clinicians use methylmethacrylate vertebroplasty to treat vertebral hemangiomas, metastases, and osteoporotic fractures. Cement may leak out of the vertebral body and compress the adjacent spinal cord and nerve roots. We review a case of nerve-root
Daniel S Thoma et al.
Journal of periodontal & implant science, 49(3), 171-184 (2019-07-10)
To evaluate the effects of intra-alveolar socket grafting, subepithelial connective tissue grafts, and individualized abutments on peri-implant hard and soft tissue outcomes following immediate implant placement. This randomized experimental study employed 5 mongrel dogs, with 4 sites per dog (total
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Materials (Basel, Switzerland), 13(3) (2020-01-25)
N,N-Dimethylacetamide (DMA) is FDA approved as an excipient and is used as drug-delivery vehicle. Due to its amphipathic nature and diverse bioactivities, it appears to be a good combination of biodegradable poly-lactide-co-glycolide (PLGA)-based guided bone regeneration membranes. Here we show
Liangjing Xin et al.
Frontiers in bioengineering and biotechnology, 8, 600032-600032 (2020-12-17)
Schneiderian membrane (SM) perforation is a major complication of maxillary sinus elevation with simultaneous bone grafting, yet under this scenario there is no standard biomaterial that maximizes favorable tissue healing and osteogenic effects. To compare the effect of advanced platelet-rich
Kevin N Johnson et al.
The Annals of thoracic surgery, 99(6), 1936-1943 (2015-04-30)
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Protocols

ARGET ATRP: Procedure for PMMA Polymer Brush Growth

We presents an article about ARGET ATRP, and its procedure for PMMA polymer brush growth. Surface preparation before polymer brush growth consists of two steps: surface cleaning and initiator monolayer deposition.

Preparation of Monodisperse Polymer Spheres

Monodisperse, surfactant-free polymer spheres for use as colloidal crystal templates can be easily obtained in reasonably large quantities. Typical synthesis methods for poly(methyl methacrylate) (PMMA) and poly(styrene) (PS) by emulsifier free emulsion polymerization are described below and yield spheres several hundred nanometers in diameter.

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