- Flavin-cyclodextrin conjugates as catalysts of enantioselective sulfoxidations with hydrogen peroxide in aqueous media.
Flavin-cyclodextrin conjugates as catalysts of enantioselective sulfoxidations with hydrogen peroxide in aqueous media.
Chemical communications (Cambridge, England) (2010-09-14)
Viktor Mojr, Vladimír Herzig, Miloš Buděšínský, Radek Cibulka, Tomáš Kraus
PMID20835467
ABSTRACT
β-Cyclodextrin-flavin conjugates are highly efficient catalysts for the sulfoxidation of methyl phenyl sulfides with hydrogen peroxide in neat aqueous media operating at loadings down to 0.2 mol% and allowing for enantioselectivities up to 80% ee.
MATERIALS