Skip to Content
MilliporeSigma
  • DBU-catalyzed tandem additions of electron-deficient 1,3-conjugated enynes with 2-aminomalonates: a facile access to highly substituted 2-pyrrolines.

DBU-catalyzed tandem additions of electron-deficient 1,3-conjugated enynes with 2-aminomalonates: a facile access to highly substituted 2-pyrrolines.

Chemical communications (Cambridge, England) (2012-03-17)
Xiuzhao Yu, Guanghua Zhou, Junliang Zhang
ABSTRACT

An efficient, metal free approach to highly substituted 2-pyrrolines by DBU-catalyzed tandem additions (a formal [3+2] cycloaddition) of electron-deficient 1,3-conjugated enynes and 2-aminomalonates under mild conditions was developed.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
1,8-Diazabicyclo[5.4.0]undec-7-ene, 98%
Sigma-Aldrich
1,8-Diazabicyclo[5.4.0]undec-7-ene, puriss., ≥99.0% (GC)