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  • FeCl3-catalyzed cyclization of α-sulfonamido-allenes with aldehydes--the substituent effect.

FeCl3-catalyzed cyclization of α-sulfonamido-allenes with aldehydes--the substituent effect.

Chemical communications (Cambridge, England) (2012-11-09)
Jiajia Cheng, Xinjun Tang, Yihua Yu, Shengming Ma
ABSTRACT

FeCl(3)-catalyzed aza-Prins-cyclization reaction of α-sulfonamido-allenes with aldehydes afforded 1,2,3,6-tetrahydropyridine or 2,5-dihydro-1H-pyrrole derivatives efficiently and highly selectively. The different regioselectivity is probably caused by the stabilizing effect of the phenyl group on the positively charged allylic intermediate.

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Iron(III) chloride, sublimed grade, ≥99.9% trace metals basis
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Iron(III) chloride, anhydrous, powder, ≥99.99% trace metals basis
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Iron(III) chloride hexahydrate, puriss. p.a., reag. Ph. Eur., ≥99%
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Iron(III) chloride hexahydrate, puriss. p.a., ACS reagent, crystallized, 98.0-102% (RT)
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