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Transfer of eight phthalates through the milk chain--a case study.

Environment international (2012-11-10)
T Fierens, M Van Holderbeke, H Willems, S De Henauw, I Sioen
ABSTRACT

This survey determined the levels of eight phthalates - i.e. dimethyl phthalate (DMP), diethyl phthalate (DEP), diisobutyl phthalate (DiBP), di-n-butyl phthalate (DnBP), benzylbutyl phthalate (BzBP), di(2-ethylhexyl) phthalate (DEHP), dicyclohexyl phthalate (DCHP) and di-n-octyl phthalate (DnOP) - in several Belgian milk and dairy products. Samples were obtained from various farms, a dairy factory and from different shops in order to investigate phthalate contamination "from farm to fork". At several stages in the milk chain, product contamination with phthalates - mostly DiBP, DnBP, BzBP and DEHP - was observed. At farm level, the mechanical milking process and the intake of phthalate containing feed by the cattle were found to be possible contamination sources. At industry and retail level, contact materials including packaging materials were additional contamination sources for phthalates in milk and dairy products.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Phthalic acid, SAJ special grade, ≥99.0%
Sigma-Aldrich
Dibutyl phthalate, SAJ special grade, ≥98.0%
Supelco
Diisobutyl phthalate, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Sigma-Aldrich
Bis(2-ethylhexyl) phthalate, SAJ first grade, ≥98.0%
Supelco
Bis(2-ethylhexyl) phthalate, Selectophore
Sigma-Aldrich
Dioctyl phthalate, ≥99.5%
Supelco
Dibutyl phthalate, PESTANAL®, analytical standard
Supelco
Dimethyl phthalate, PESTANAL®, analytical standard
Sigma-Aldrich
Dimethyl phthalate, ≥99%
Supelco
Di-n-butyl phthalate solution, certified reference material, 5000 μg/mL in methanol
Sigma-Aldrich
Dicyclohexyl phthalate, 99%
Sigma-Aldrich
Dimethyl phthalate, ≥99%
Sigma-Aldrich
Diisobutyl phthalate, 99%
Supelco
Bis(2-ethylhexyl) phthalate, PESTANAL®, analytical standard
Sigma-Aldrich
Potassium hydrogen phthalate, BioXtra, ≥99.95%
Supelco
Dibutyl phthalate, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Supelco
Bis(2-ethylhexyl) phthalate, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Sigma-Aldrich
Dimethyl phthalate, SAJ special grade, ≥99.0%
Sigma-Aldrich
Dibutyl phthalate, 99%
Sigma-Aldrich
Phthalic acid, puriss. p.a., ≥99.5% (T)
Sigma-Aldrich
Phthalic acid, reagent grade, 98%
Sigma-Aldrich
Phthalic acid, ACS reagent, ≥99.5%
Sigma-Aldrich
Potassium phthalate monobasic, JIS special grade, 99.8-100.2%
Supelco
Potassium phthalate monobasic, Standard for quantitative NMR, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Sigma-Aldrich
Diethyl phthalate, SAJ special grade, ≥98.0%
Supelco
Bis(2-ethylhexyl) phthalate solution, certified reference material, 2000 μg/mL in methanol
Supelco
Di-n-octyl phthalate, analytical standard
Sigma-Aldrich
Diethyl phthalate, ≥99%
Sigma-Aldrich
Potassium phthalate monobasic, BioUltra, ≥99.5% (T)
Supelco
Diethyl phthalate, PESTANAL®, analytical standard