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  • Hydrogen sulfide removal from livestock biogas by a farm-scale bio-filter desulfurization system.

Hydrogen sulfide removal from livestock biogas by a farm-scale bio-filter desulfurization system.

Water science and technology : a journal of the International Association on Water Pollution Research (2013-03-20)
J-J Su, Y-C Chang, Y-J Chen, K-C Chang, S-Y Lee
ABSTRACT

A farm-scale biogas desulfurization system was designed and tested for H2S removal efficiency from livestock biogas. This work assesses the H2S removal efficiency of a novel farm-scale biogas bio-desulfurization system (BBS) operated for 350 days on a 1,000-head pig farm. Experimental data demonstrated that suitable humidity and temperature can help sulfur-oxidizing bacteria to form active bio-films on the bio-carriers. The daily average removal rate increased to 879.16 from 337.75 g-H2S/d with an average inlet H2S concentration of 4,691 ± 1,532 mg/m(3) in biogas. Thus, the overall (0-350 days) average H2S removal efficiency exceeded 93%. The proposed BBS overcomes limitations of H2S in biogas when utilizing pig farm biogas for power generation and other applications.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Hydrogen sulfide, ≥99.5%
Supelco
Sulfur, PESTANAL®, analytical standard
Sigma-Aldrich
Sulfur, flakes, ≥99.99% trace metals basis
Sigma-Aldrich
Sulfur, powder, 99.98% trace metals basis
Sigma-Aldrich
Sulfur, 99.998% trace metals basis
Sigma-Aldrich
Hydrogen sulfide solution, 0.8 M in THF