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  • Methyl ricinoleate as platform chemical for simultaneous production of fine chemicals and polymer precursors.

Methyl ricinoleate as platform chemical for simultaneous production of fine chemicals and polymer precursors.

ChemSusChem (2012-09-27)
Antoine Dupé, Mathieu Achard, Cédric Fischmeister, Christian Bruneau
ABSTRACT

The modification of methyl ricinoleate by etherification of the hydroxyl group was accomplished by using a nonclassical ruthenium-catalyzed allylation reaction and also by esterification. Methyl ricinoleate derivatives were engaged in ring-closing metathesis (RCM) reactions leading to biosourced 3,6-dihydropyran and α,β-unsaturated lactone derivatives with concomitant production of polymer precursors. Sequential RCM/hydrogenation and RCM/cross-metathesis were also implemented as a straightforward method for the synthesis of tetrahydropyran and lactone derivatives as well as valuable monomers (i.e., polyamide precursors).

MATERIALS
Product Number
Brand
Product Description

Supelco
Methyl ricinoleate, analytical standard
Sigma-Aldrich
Methyl ricinoleate, ≥99% (GC)