- Stereospecific Ni-catalyzed cross-coupling of potassium alkenyltrifluoroborates with alkyl halides.
Stereospecific Ni-catalyzed cross-coupling of potassium alkenyltrifluoroborates with alkyl halides.
Organic letters (2014-03-29)
Gary A Molander, O Andreea Argintaru
PMID24666316
ABSTRACT
A general method for the alkenylation of alkyl electrophiles using nearly stoichiometric amounts of the air- and moisture-stable potassium organotrifluoroborates has been developed. Various functional groups were tolerated on both the nucleophilic and electrophilic partner. Reactions of highly substituted E- and Z-alkenyltrifluoroborates, as well as vinyl- and propenyltrifluoroborates, were successful, and no loss of stereochemistry or regiochemistry was observed.
MATERIALS
Product Number
Brand
Product Description
Nickel, foil, 6mm disks, thickness 0.009mm, 99.95%
Nickel, foil, not light tested, 100x100mm, thickness 0.004mm, hard, 99%
Nickel, foil, not light tested, 25x25mm, thickness 0.001mm, 99.95%
Nickel, foil, not light tested, 100x100mm, thickness 0.002mm, 99.95%
Nickel, foil, light tested, 25x25mm, thickness 0.009mm, 99.95%
Nickel, foil, not light tested, 25x25mm, thickness 0.0005mm, temporary acrylic support, 99.95%
Nickel, foil, light tested, 100x100mm, thickness 0.007mm, 99.95%
Nickel, tube, 500mm, outside diameter 1.0mm, inside diameter 0.8mm, wall thickness 0.1mm, hard, 99.5%
Nickel, foil, 10m coil, thickness 0.125mm, coil width 50mm, annealed, 99%
Nickel, pellets, 20g, max. size 20mm, 99.99+%
Nickel, foil, 0.5m coil, thickness 0.125mm, annealed, 99%
Nickel, foil, 0.5m coil, thickness 0.005mm, as rolled, 99.9%
Nickel, wire reel, 1m, diameter 0.4mm, as drawn, 99.99+%
Nickel, foil, 0.5m coil, thickness 0.0075mm, 99.95%
Nickel, foil, 25x25mm, thickness 0.25mm, as rolled, 99.999%
Nickel, wire reel, 10m, diameter 0.01mm, as drawn, 99.98%
Nickel, foil, 5m coil, thickness 0.15mm, coil width 12mm, annealed, 99%
Nickel, foil, 50mm disks, thickness 0.005mm, as rolled, 99.9%
Nickel, foil, 5m coil, thickness 0.025mm, annealed, 99%
Nickel, foil, 50mm disks, thickness 0.025mm, annealed, 99%
Nickel, foil, 4mm disks, thickness 0.3mm, as rolled, 100%
Nickel, rod, 100mm, diameter 12.0mm, 99%
Nickel, foil, 10mm disks, thickness 0.003mm, 99.95%
Nickel, pellets, 50g, max. size 5mm, 99.99+%