MilliporeSigma

High-valent organometallic copper and palladium in catalysis.

Nature (2012-04-14)
Amanda J Hickman, Melanie S Sanford
ABSTRACT

Copper and palladium catalysts are critically important in numerous commercial chemical processes. Improvements in the activity, selectivity and scope of these catalysts could drastically reduce the environmental impact, and increase the sustainability, of chemical reactions. One rapidly developing strategy for achieving these goals is to use 'high-valent' organometallic copper and palladium intermediates in catalysis. Here we describe recent advances involving both the fundamental chemistry and the applications of these high-valent metal complexes in numerous synthetically useful catalytic transformations.

MATERIALS
Product Number
Brand
Product Description

Palladium, foil, not light tested, 100x100mm, thickness 0.025mm, as rolled, 99.99+%
Palladium, foil, not light tested, 25x25mm, thickness 0.00075mm, permanent polyester support, 99.75%
Palladium, tube, 50mm, outside diameter 1.0mm, inside diameter 0.8mm, wall thickness 0.1mm, as drawn, 99.95%
Palladium, microfoil, disks, 10mm, thinness 0.5μm, specific density 303.4μg/cm2, permanent mylar 3.5μm support, 99.99%
Palladium, foil, 10mm disks, thickness 0.025mm, as rolled, 99.99+%
Palladium, foil, not light tested, 50x50mm, thickness 0.004mm, 99.95%
Palladium, foil, 25x25mm, thickness 0.50mm, as rolled, 99.95%
Palladium, foil, 10mm disks, thickness 0.25mm, as rolled, 99.95%
Palladium, foil, 4mm disks, thickness 0.075mm, as rolled, 99.95%
Palladium, foil, 25x25mm, thickness 0.1mm, as rolled, 99.99+%
Palladium, foil, 10mm disks, thickness 0.125mm, as rolled, 99.95%
Palladium, foil, light tested, 50x50mm, thickness 0.03mm, as rolled, 99.95%
Palladium, foil, light tested, 50x50mm, thickness 0.075mm, as rolled, 99.95%
Palladium, foil, 8mm disks, thickness 0.25mm, as rolled, 99.95%
Palladium, foil, not light tested, 25x25mm, thickness 0.004mm, 99.95%
Palladium, foil, not light tested, 50x50mm, thickness 0.03mm, as rolled, 99.95%
Palladium, foil, not light tested, 50x50mm, thickness 0.002mm, 99.95%
Palladium, foil, not light tested, 150x150mm, thickness 0.0125mm, 99.95%
Palladium, microfoil, disks, 10mm, thinness 0.1μm, specific density 119.2μg/cm2, permanent mylar 3.5μm support, 99.99%
Palladium, foil, light tested, 25x25mm, thickness 0.047mm, as rolled, 99.95%
Palladium, tube, 100mm, outside diameter 2.0mm, inside diameter 1.6mm, wall thickness 0.2mm, as drawn, 99.95%
Palladium, microfoil, disks, 50mm, thinness 0.1μm, specific density 119.2μg/cm2, permanent mylar 3.5μm support, 99.99%
Palladium, foil, not light tested, 25x25mm, thickness 0.025mm, as rolled, 99.99+%
Palladium, foil, not light tested, 25x25mm, thickness 0.006mm, 99.95%
Palladium, rod, 25mm, diameter 6.0mm, 99.95%
Palladium, foil, not light tested, 25x25mm, thickness 0.001mm, permanent polyester support, 99.75%
Palladium, wire reel, 2m, diameter 0.25mm, as drawn, 99.99+%
Palladium, wire reel, 0.1m, diameter 0.125mm, hard, 99.95%
Palladium, tube, 120mm, outside diameter 6mm, inside diameter 5mm, wall thickness 0.5mm, as drawn, 99.95%
Palladium, wire reel, 1m, diameter 0.25mm, as drawn, 99.99+%