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  • Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Molecules (Basel, Switzerland) (2013-05-28)
Jana Doháňošová, Tibor Gracza
ABSTRACT

The palladium (II)-catalysed reactions of alkenols and aminoalkenols such as oxycarbonylations or bicyclisations are powerful methods for the construction of oxygen and nitrogen-containing heterocyclic compounds. This review highlights recent progress in the development of the asymmetric palladium(II)-catalysed Wacker-type cyclisations of unsaturated polyols and aminoalcohols. The scope, limitations, and applications of these reactions are presented.

MATERIALS
Product Number
Brand
Product Description

Palladium, foil, not light tested, 100x100mm, thickness 0.025mm, as rolled, 99.99+%
Palladium, foil, not light tested, 25x25mm, thickness 0.00075mm, permanent polyester support, 99.75%
Palladium, tube, 50mm, outside diameter 1.0mm, inside diameter 0.8mm, wall thickness 0.1mm, as drawn, 99.95%
Palladium, microfoil, disks, 10mm, thinness 0.5μm, specific density 303.4μg/cm2, permanent mylar 3.5μm support, 99.99%
Palladium, foil, 10mm disks, thickness 0.025mm, as rolled, 99.99+%
Palladium, foil, not light tested, 50x50mm, thickness 0.004mm, 99.95%
Palladium, foil, 25x25mm, thickness 0.50mm, as rolled, 99.95%
Palladium, foil, 10mm disks, thickness 0.25mm, as rolled, 99.95%
Palladium, foil, 4mm disks, thickness 0.075mm, as rolled, 99.95%
Palladium, foil, 25x25mm, thickness 0.1mm, as rolled, 99.99+%
Palladium, foil, 10mm disks, thickness 0.125mm, as rolled, 99.95%
Palladium, foil, light tested, 50x50mm, thickness 0.03mm, as rolled, 99.95%
Palladium, foil, light tested, 50x50mm, thickness 0.075mm, as rolled, 99.95%
Palladium, foil, 8mm disks, thickness 0.25mm, as rolled, 99.95%
Palladium, foil, not light tested, 25x25mm, thickness 0.004mm, 99.95%
Palladium, foil, not light tested, 50x50mm, thickness 0.03mm, as rolled, 99.95%
Palladium, foil, not light tested, 50x50mm, thickness 0.002mm, 99.95%
Palladium, foil, not light tested, 150x150mm, thickness 0.0125mm, 99.95%
Palladium, microfoil, disks, 10mm, thinness 0.1μm, specific density 119.2μg/cm2, permanent mylar 3.5μm support, 99.99%
Palladium, foil, light tested, 25x25mm, thickness 0.047mm, as rolled, 99.95%
Palladium, tube, 100mm, outside diameter 2.0mm, inside diameter 1.6mm, wall thickness 0.2mm, as drawn, 99.95%
Palladium, microfoil, disks, 50mm, thinness 0.1μm, specific density 119.2μg/cm2, permanent mylar 3.5μm support, 99.99%
Palladium, foil, not light tested, 25x25mm, thickness 0.025mm, as rolled, 99.99+%
Palladium, foil, not light tested, 25x25mm, thickness 0.006mm, 99.95%
Palladium, rod, 25mm, diameter 6.0mm, 99.95%
Palladium, foil, not light tested, 25x25mm, thickness 0.001mm, permanent polyester support, 99.75%
Palladium, wire reel, 2m, diameter 0.25mm, as drawn, 99.99+%
Palladium, wire reel, 0.1m, diameter 0.125mm, hard, 99.95%
Palladium, tube, 120mm, outside diameter 6mm, inside diameter 5mm, wall thickness 0.5mm, as drawn, 99.95%
Palladium, wire reel, 1m, diameter 0.25mm, as drawn, 99.99+%