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Merck

935719

Sigma-Aldrich

硝酸コバルト(II) 六水和物

greener alternative

≥99.9% trace metals basis

別名:

硝酸、コバルト(II)塩, 硝酸コバルト, 硝酸第一コバルト 六水和物

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About This Item

化学式:
Co(NO3)2 · 6H2O
CAS番号:
分子量:
291.03
MDL番号:
UNSPSCコード:
12352302
NACRES:
NA.21

品質水準

アッセイ

≥99.9% trace metals basis

形状

powder, crystals or granules (Chunks)

環境により配慮した代替製品の特徴

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

faint red to very dark red

mp

55 °C (lit.)

溶解性

soluble, clear to slightly hazy

環境により配慮した代替製品カテゴリ

SMILES記法

O.O.O.O.O.O.[Co++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Co.2NO3.6H2O/c;2*2-1(3)4;;;;;;/h;;;6*1H2/q+2;2*-1;;;;;;

InChI Key

QGUAJWGNOXCYJF-UHFFFAOYSA-N

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詳細

Cobalt(II)nitrate hexahydrate is red solid which is soluble in water and polar solvents. It is also known as hexaaquacobalt(II) nitrate consists of [Co(OH2)6]2+ and [NO3]ions.
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アプリケーション

Cobalt(II) nitrate hexahydrate, has been widely used for the synthesis of Cobalt oxide nanoparticles and cobalt containing compounds. For Example:Cobalt(II) nitrate hexahydrate is used to synthesize cobalt-cobalt oxide/N-doped carbon hybrids, which are then used as hydrogen evolution reaction (HER) or superior oxygen evolution reaction (OER) catalysts in water splitting.

It has also been used as a primary precursor material in the synthesis of Co3O4 nanocrystals in various shapes such as nanosheets, nanocubes, and nanobelts as a catalyst for methane combustion.

Furthermore, the reaction of Cobalt(II) nitrate hexahydrate with Nickel(II) nitrate hexahydrate produces Nickel-cobalt layered double hydroxide nanosheets in presence of methanol and CTAB, which is used as a high-performance electrocatalyst for oxygen evolution.

In addition, Cobalt(II) nitrate hexahydrate precursor powder is calcined to produce Co3O4 nanotubes using the template synthesis method. The Co3O4 nano-tubes, nanorods, and nanoparticles that have been created are used in gas sensing systems and as anode materials for Li-ion batteries

Cobalt hydroxide and layered double hydroxides (CH@LDH) have been synthesized using Cobalt(II)nitrate hexahydrate as a sulfur host for lithium–sulfur batteries.

It is well studied that, Cobalt(II) nitrate hexahydrate is used as a heterogeneous catalyst Co/SiO2 with Silica support, for Fischer−Tropsch Synthesis.

Cobalt(II) Nitrate Hexahydrate is also used as a catalyst for the synthesis of 5-Carboxanilide-dihydropyrimidinone derivatives by the condensation reaction of acetoacetanilide, aldehyde and urea/thiourea.

シグナルワード

Danger

危険有害性の分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 2 Inhalation

ターゲットの組織

Lungs

保管分類コード

5.1B - Oxidizing hazardous materials

WGK

WGK 3

引火点(°F)

Not applicable

引火点(℃)

Not applicable


適用法令

試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。

PRTR

第一種指定化学物質

労働安全衛生法名称等を表示すべき危険物及び有害物

名称等を表示すべき危険物及び有害物

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Jan Code

935719-25G:
935719-VAR:
935719-BULK:
935719-250G:


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Fundamentals of melt infiltration for the preparation of supported metal catalysts. The case of Co/SiO2 for Fischer-Tropsch synthesis
Eggenhuisen T M, et al.
Journal of the American Chemical Society, 132, 18318-18325 (2010)
Nickel?cobalt layered double hydroxide nanosheets as high-performance electrocatalyst for oxygen evolution reaction
Jiang J, et al.
Journal of Power Sources, 278, 445-451 (2015)
Selective catalytic reduction of nitrogen oxides by ammonia over Co3O4 nanocrystals with different shapes
Meng B, et al.
Applied Catalysis. B, Environmental, 129, 491-500 (2013)
Double-Shelled Nanocages with Cobalt Hydroxide Inner Shell and Layered Double Hydroxides Outer Shell as High-Efficiency Polysulfide Mediator for Lithium-Sulfur Batteries
Zhang J, et al.
Angewandte Chemie (International ed. in English), 55, 3982-3986 (2016)
In situ cobalt-cobalt oxide/N-doped carbon hybrids as superior bifunctional electrocatalysts for hydrogen and oxygen evolution
Jin H, et al.
Journal of the American Chemical Society, 137, 2688-2694 (2015)

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