936839

AdBrettPhos ChemBeads

• 別名: Di-Ad-BrettPhos ChemBeads, Diadamantan-1-yl)(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphane ChemBeads
• 実験式（ヒル表記法）: C₄₃H₆₁O₂P
• CAS番号: 1160861-59-5
• 分子量: 640.92
• UNSPSCコード: 12352100

特性

• フォーム: solid
• 品質水準: 100
• 組成: , 4-6% (loading)
• 反応適合性: reagent type: ligand
• SMILES記法: COC1=CC=C(C(C2=C(C=C(C=C2C(C)C)C(C)C)C(C)C)=C1P([C@]34C[C@H]5C[C@H](C[C@H](C5)C4)C3)[C@]67C[C@H]8C[C@H](C[C@H](C8)C7)C6)OC
• InChI: InChI=1S/C43H61O2P/c1-25(2)34-17-35(26(3)4)39(36(18-34)27(5)6)40-37(44-7)9-10-38(45-8)41(40)46(42-19-28-11-29(20-42)13-30(12-28)21-42)43-22-31-14-32(23-43)16-33(15-31)24-43/h9-10,17-18,25-33H,11-16,19-24H2,1-8H3/t28-,29+,30-,31-,32+,33-,42?,43?,46?
• InChI Key: NMGHOZQCYNKWBG-DQMWLEPPSA-N

詳細

詳細

The AdBrettPhos ligand coated of glass beads. AdBrettPhos is a phosphine-based ligand used in the direct monoarylation of ammonia and suppresses diarylation. In addition, it is a good ligand for five-membered heteroarene couplings and is employed in the preparation of phosphine-ligated palladium complexes to facilitate C-N coupling reactions. For use in high-throughput expermentation (HTE).

アプリケーション

AdBrettPhos has been used in:
C-N Coupling reactions. (see 31896889)
The fluorination of alrl triflates.(see 25346547)
The Palladium-Catalyzed C-O Cross-Coupling of Primary Alcohols. (see 29474078)
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
For general uses, product is also available in powdered form (768154)

安全性情報

• 保管分類コード: 13 - Non Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable