180211
Borane tert-butylamine complex
powder, 97%
동의어(들):
tert-Butylamine borane, NSC 114045, Trihydro(2-methyl-2-propanamine) boron
로그인조직 및 계약 가격 보기
모든 사진(3)
About This Item
Linear Formula:
(CH3)3CNH2 · BH3
CAS Number:
Molecular Weight:
86.97
EC Number:
MDL number:
UNSPSC 코드:
12352116
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Quality Level
분석
97%
양식
powder
반응 적합성
reagent type: reductant
mp
98-100 °C (dec.) (lit.)
작용기
amine
SMILES string
B.CC(C)(C)N
InChI
1S/C4H11N.BH3/c1-4(2,3)5;/h5H2,1-3H3;1H3
InChI key
GKFJEDWZQZKYHV-UHFFFAOYSA-N
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일반 설명
Borane tert-butylamine complex is a mild reducing agent. It participates in the selective reduction of aldehydes and ketones to corresponding alcohol. It takes part as a reducing agent in the synthesis of monodisperse palladium nanoparticles (Pd NPs), monodisperse gold (Au) nanoparticles and carbon-supported Pd electrocatalysts.
애플리케이션
Borane tert-butylamine (BTB) complex may be used as strong co-reducing agent in the following syntheses:
- copper (I) oxide nanoparticles
- diphosphine-protected gold nanocluster
- 4-acetoxycinnamyl alcohols
Reactant involved in:
- Non-destructive analyses and conservation treatments of Indian drawings
- Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium / iridium bis(N-heterocyclic carbene) complexes
- The formation of σ-borane complexes
- Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins
- Photochemical hydroboration and oxidation of single-walled carbon nanotubes
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
이미 열람한 고객
A facile synthesis of monodisperse Au nanoparticles and their catalysis of CO oxidation.
Peng S, et al.
Nano Research, 1(3), 229-234 (2008)
Na Rae Kim et al.
Journal of nanoscience and nanotechnology, 13(9), 6027-6032 (2013-11-12)
To control the optical properties of Cu2O for a variety of application, we synthesized Cu2O in nanoscale without other treatments. Cu2O nanoparticles with an average size of 2.7 nm (sigma < or = 3.7%) were successfully synthesized in this study
John M Pettibone et al.
Physical chemistry chemical physics : PCCP, 14(12), 4142-4154 (2012-02-18)
We identify the reaction network governing gold monolayer protected cluster (MPC) formation during the reduction of Au(PPh(3))Cl and L(5) (L(5) = 1,5-bis(diphenylphosphino)pentane) in solutions. UV-vis spectroscopy and electrospray ionization mass spectrometry (ESI-MS) monitored the formation of ligated Au(x): 6 ≤
Hydrolytic dehydrogenation of ammonia borane catalyzed by reduced graphene oxide supported monodisperse palladium nanoparticles: High activity and detailed reaction kinetics.
Kilic B, et al.
J. Mol. Catal. A: Chem., 361, 104-110 (2012)
Reductive deoxygenation of aryl aldehydes and ketones by tert-butylamine-borane and aluminum chloride.
Lau CK, et al.
The Journal of Organic Chemistry, 54(2), 491-494 (1989)
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