180211
Borane tert-butylamine complex
powder, 97%
동의어(들):
tert-Butylamine borane, NSC 114045, Trihydro(2-methyl-2-propanamine) boron
로그인조직 및 계약 가격 보기
모든 사진(3)
About This Item
Linear Formula:
(CH3)3CNH2 · BH3
CAS Number:
Molecular Weight:
86.97
EC Number:
MDL number:
UNSPSC 코드:
12352116
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Quality Level
분석
97%
양식
powder
반응 적합성
reagent type: reductant
mp
98-100 °C (dec.) (lit.)
작용기
amine
SMILES string
B.CC(C)(C)N
InChI
1S/C4H11N.BH3/c1-4(2,3)5;/h5H2,1-3H3;1H3
InChI key
GKFJEDWZQZKYHV-UHFFFAOYSA-N
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일반 설명
Borane tert-butylamine complex is a mild reducing agent. It participates in the selective reduction of aldehydes and ketones to corresponding alcohol. It takes part as a reducing agent in the synthesis of monodisperse palladium nanoparticles (Pd NPs), monodisperse gold (Au) nanoparticles and carbon-supported Pd electrocatalysts.
애플리케이션
Borane tert-butylamine (BTB) complex may be used as strong co-reducing agent in the following syntheses:
- copper (I) oxide nanoparticles
- diphosphine-protected gold nanocluster
- 4-acetoxycinnamyl alcohols
Reactant involved in:
- Non-destructive analyses and conservation treatments of Indian drawings
- Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium / iridium bis(N-heterocyclic carbene) complexes
- The formation of σ-borane complexes
- Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins
- Photochemical hydroboration and oxidation of single-walled carbon nanotubes
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
이미 열람한 고객
Hydrolytic dehydrogenation of ammonia borane catalyzed by reduced graphene oxide supported monodisperse palladium nanoparticles: High activity and detailed reaction kinetics.
Kilic B, et al.
J. Mol. Catal. A: Chem., 361, 104-110 (2012)
Reductive deoxygenation of aryl aldehydes and ketones by tert-butylamine-borane and aluminum chloride.
Lau CK, et al.
The Journal of Organic Chemistry, 54(2), 491-494 (1989)
Facile synthesis of 4-hydroxycinnamyl p-coumarates.
Lu C and Raplph J.
Journal of Agricultural and Food Chemistry, 46(8), 2911-2913 (1998)
Supported core@ shell electrocatalysts for fuel cells: close encounter with reality.
Hwang SJ, et al.
Scientific Reports, 3 (2013)
A facile synthesis of monodisperse Au nanoparticles and their catalysis of CO oxidation.
Peng S, et al.
Nano Research, 1(3), 229-234 (2008)
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