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Merck
모든 사진(1)

문서

185124

Sigma-Aldrich

Dimethyl terephthalate

ReagentPlus®, ≥99%

동의어(들):

DMT, Dimethyl 1,4-benzenedicarboxylate, Dimethyl p-benzenedicarboxylate, Dimethyl p-phthalate, Methyl 4-(carbomethoxy)benzoate

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About This Item

Linear Formula:
C6H4-1,4-(CO2CH3)2
CAS Number:
Molecular Weight:
194.18
Beilstein:
1107185
EC Number:
MDL number:
UNSPSC 코드:
12352100
eCl@ss:
39024601
PubChem Substance ID:
NACRES:
NA.22

vapor density

1.04 (vs air)

vapor pressure

1.15 mmHg ( 93 °C)

제품 라인

ReagentPlus®

분석

≥99%

형태

(Powder or Crystals or Chunk(s))

autoignition temp.

1058 °F

mp

139-141 °C (lit.)

solubility

water: slightly soluble 0.0493 g/L at 20 °C

SMILES string

COC(=O)c1ccc(cc1)C(=O)OC

InChI

1S/C10H10O4/c1-13-9(11)7-3-5-8(6-4-7)10(12)14-2/h3-6H,1-2H3

InChI key

WOZVHXUHUFLZGK-UHFFFAOYSA-N

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일반 설명

Dimethyl terephthalate undergoes enzymatic polycondensation with 1,8-diaminooctane to yield oligo(octamethylene terephthalamide).

애플리케이션

Dimethyl terephthalate was used to synthesize silicone aromatic polyesters by the transesterification reaction with α,ω-bis(hydroxyalkyl)-terminated poly(dimethylsiloxane) in toluene. It was used in the synthesis of multiblock copolymers consisting of polyiso-butylene, dimethyl terephthalate and 1,4-butanediol.

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point (°F)

309.2 °F - (External MSDS)

Flash Point (°C)

154 °C - (External MSDS)

개인 보호 장비

Eyeshields, Gloves, type N95 (US)


시험 성적서(COA)

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문서 라이브러리 방문

Copolyesters containing polyisobutylene soft segments and polybutylene terephthalate as the crystalline segments.
Deak G and Kennedy JP.
Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 33(S7-8), 439-449 (1996)
Yadagiri Poojari et al.
Chemical communications (Cambridge, England), (44)(44), 6834-6835 (2009-11-04)
Immobilized Candida antarctica lipase B (CALB) was successfully employed as a catalyst to synthesize silicone aromatic polyesters by the transesterification of dimethyl terephthalate with alpha,omega-bis(hydroxyalkyl)-terminated poly(dimethylsiloxane) in toluene under mild reaction conditions.
E Stavila et al.
Biomacromolecules, 14(5), 1600-1606 (2013-04-03)
Enzymatically catalyzed polycondensation of p-xylylenediamine and diethyl sebacate resulted in oligo(p-xylylene sebacamide) with high melting temperatures (223-230 °C) and the enzymatic polycondensation of dimethyl terephthalate and 1,8-diaminooctane leads to oligo(octamethylene terephthalamide) with two melting temperatures at 186 and 218 °C.
Tristan A Geervliet et al.
Chemistry, an Asian journal, 14(6), 877-883 (2018-12-15)
This study reports for the first time the use of bio-based alternatives for PMMA as host matrix for luminescent solar concentrators (LSCs). Notably, two types of renewable polyesters were synthesized in varying molar ratios via a two-step melt-polycondensation reaction with
S Monarca et al.
Mutation research, 262(2), 85-92 (1991-02-01)
Dimethyl terephthalate (DMTP), the para configuration of dimethyl phthalate, is one of the basic monomers used in the synthesis of polyethylene terephthalate (PET) plastics. Human exposure to DMTP may primarily occur during the manufacture of PET fibers and films. The

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