추천 제품
Quality Level
분석
95%
형태
liquid
refractive index
n20/D 1.584 (lit.)
bp
108 °C/12 mmHg (lit.)
mp
−19 °C (lit.)
density
1.096 g/mL at 25 °C (lit.)
저장 온도
2-8°C
SMILES string
ClC\C=C\c1ccccc1
InChI
1S/C9H9Cl/c10-8-4-7-9-5-2-1-3-6-9/h1-7H,8H2/b7-4+
InChI key
IWTYTFSSTWXZFU-QPJJXVBHSA-N
일반 설명
Cinnamyl chloride reacts regioselectively with aryl and alkenylgold(I) phosphanes in the presence of palladium catalyst in THF to afford the α-substitution product†.
애플리케이션
Cinnamyl chloride was used in the enantioselective total synthesis of helioporins C and E, bioactive marine diterpenes.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Muta. 2 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1B - STOT RE 2
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point (°F)
174.2 °F - closed cup
Flash Point (°C)
79 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
이미 열람한 고객
Juan Carlos Rueda et al.
Polymers, 12(6) (2020-06-26)
Stiff thermosensitive hydrogels (HG) were synthesized by self-crosslinking free radical polymerization of N,N-dimethylacrylamide (DMAA) and N-isopropylacrylamide (NIPAAm), adjusting the degree of swelling by carboxylate-containing sodium acrylate (NaAc) or a 2-oxazoline macromonomer (MM). The formation of hydrogels was possible due to
Wibke Lölsberg et al.
Organic letters, 14(23), 5996-5999 (2012-11-15)
A short and enantioselective total synthesis of helioporins C and E, which are bioactive marine diterpenes containing a serrulatane or amphilectane skeleton, was elaborated. The chirogenic step, i.e. a Cu(I)-catalyzed allylic alkylation of a cinnamyl chloride with methylmagnesium bromide, proceeded
Palladium-catalyzed cross-coupling reactions of organogold(I) phosphanes with allylic electrophiles.
Miguel Peña-López et al.
Organic & biomolecular chemistry, 10(8), 1686-1694 (2012-01-24)
Aryl and alkenylgold(I) phosphanes react regioselectively with allylic electrophiles such as cinnamyl and geranyl halides (bromide, chloride and acetates) under palladium catalysis in THF at 80 °C to afford the α-substitution product with moderate to high yields. When the reaction
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