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Merck
모든 사진(2)

주요 문서

187240

Sigma-Aldrich

9-Anthracenemethanol

97%

동의어(들):

9-(Hydroxymethyl)anthracene

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About This Item

실험식(Hill 표기법):
C15H12O
CAS Number:
Molecular Weight:
208.26
Beilstein:
1873402
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

97%

solubility

chloroform: soluble 20 mg/mL, clear to slightly hazy, light yellow to yellow

작용기

hydroxyl

SMILES string

OCc1c2ccccc2cc3ccccc13

InChI

1S/C15H12O/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9,16H,10H2

InChI key

JCJNNHDZTLRSGN-UHFFFAOYSA-N

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일반 설명

9-Anthracenemethanol participates in ring-opening polymerization of L-lactide catalyzed by alumoxane. It undergoes proton exchange reaction with potassium tert-butoxide to yield potassium 9-anthracenemethoxide.

9-Anthracenemethanol is a derivative of anthracene used in the Diels-Alder reactions.

애플리케이션

9-Anthracenemethanol can be used:
  • As a starting material to prepare 9-anthracenylmethyl-1-piperazinecarboxylate, which acts as a reagent in the determination of isocyanates using HPLC.
  • In the Diels-Alder reaction with dimethylacetylene-dicarboxylate to yield lactone derivatives.
  • As an initiator in the ring-opening polymerization of δ-valerolactone to yield poly(δ-valerolactone).
  • As a starting material in the synthesis of polymer-supported anthracene, which acts as a dienophile scavenger in cycloaddition reactions.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type N95 (US)


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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Cyclodextrin-promoted Diels Alder reactions of a polycyclic aromatic hydrocarbon under mild reaction conditions
Chaudhuri, et al.
Tetrahedron Letters, 56, 1619-1623 (2015)
Development of a new approach for total isocyanate determination using the reagent 9-anthracenylmethyl-1-piperazinecarboxylate.
Roh Y-M, et al.
Analyst, 125(9), 1691-1696 (2000)
J W Flesher et al.
Biochemical and biophysical research communications, 251(1), 239-243 (1998-10-29)
The role of electrophilic hydroxymethyl sulfate esters in the metabolic activation, DNA-damage, mutagenicity, and complete carcinogenicity of polycyclic aromatic hydrocarbons has been elucidated considerably in recent years. The observations are in agreement with a unified hypothesis which predicts that electrophilic
Synthesis of a polymer-supported anthracene and its application as a dienophile scavenger
Lei X and Porco JA
Organic Letters, 6, 795-798 (2004)
Tamuka Chidanguro et al.
Dalton transactions (Cambridge, England : 2003), 47(26), 8663-8669 (2018-06-23)
We report on the use of visible light as the driving force for the intramolecular dimerization of pendant anthracene groups on a methacrylic polymer to induce the formation of single-chain nanoparticles (SCNPs). Using a 532 nm green laser light source

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