추천 제품
Quality Level
분석
≥98%
양식
solid
반응 적합성
core: zirconium
reaction type: Polymerization Reactions
reagent type: catalyst
reaction type: Olefin Metathesis
환경친화적 대안 제품 특성
Catalysis
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sustainability
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파라미터
moisture sensitive
mp
242-245 °C (lit.)
환경친화적 대안 카테고리
, Aligned
저장 온도
2-8°C
SMILES string
Cl[Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.2ClH.Zr/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChI key
QRUYYSPCOGSZGQ-UHFFFAOYSA-L
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일반 설명
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.
Zirconocene dichloride serves as a catalyst, enabling efficient synthesis of pyrrole with high yields and simplifies the purification process economically.
Zirconocene dichloride serves as a catalyst, enabling efficient synthesis of pyrrole with high yields and simplifies the purification process economically.
애플리케이션
Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
Direct amide formation from unactivated carboxylic acids and amines
Direct amide formation from unactivated carboxylic acids and amines
Useful in the synthesis of a wide range of early-transition-metal complexes and organometallic compounds.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves
가장 최신 버전 중 하나를 선택하세요:
Chemphyschem : a European journal of chemical physics and physical chemistry, 6(9), 1929-1933 (2005-08-03)
Free Car-Parrinello molecular dynamics (CPMD) simulations of four diastereomers of the zirconium-propene complexes [{iPr(3-iPr-CpFlu)}ZriBu(C3H6)]+ (Cp=cyclopentadienyl; Flu=fluorenyl) provide valuable insight into the mechanism and stereocontrol of propene polymerization with stereorigid metallocenes. Spontaneous insertion of propene into the zirconium-isobutyl bond is not
The journal of physical chemistry. A, 114(5), 2073-2079 (2010-01-21)
Cationic zirconocene complexes are active species in Ziegler-Natta catalysis for olefin polymerization. Their structure and metal-ligand bond strength strongly influence their activity. In the present work, the infrared multiphoton dissociation (IRMPD) spectrum of mass selected Zr(C(5)H(5))(2)(OH)(CH(3)CN)(+) cations was obtained in
Chemistry (Weinheim an der Bergstrasse, Germany), 15(46), 12608-12617 (2009-11-03)
A zirconocene-mediated one-pot multicomponent synthesis process leading to the synthesis of pyrrolo[3,2-c]pyridine (5-azaindoles) and pyrrole derivatives has been developed starting from a silicon-tethered diyne and three or two different or identical organonitriles. Pyrrolo[3,2-c]pyridine and pyrrole derivatives with diverse structures and
Aldrichimica Acta, 17, 28-28 (1984)
Chemical communications (Cambridge, England), 48(95), 11626-11628 (2012-10-26)
Zirconocene dichloride (Cp(2)ZrCl(2)) has been shown to be an effective catalyst for the transamidation of primary amides with amines in cyclohexane at 80 °C in 5-24 hours. For favourable substrates, the reaction can be performed at temperatures as low as
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